Burning of oil,gases and coal are the antropogenic source of co2
Limitations of Van der waal's equation. (i) The value of 'b' is not constant but varies with pressure and temperature. (ii) The value of is not equal to 3b, but actually it is equal to, in some case; and in other cases 2b. (iii) The value of is not equal to but it is usually more than 3 for most of the gases.
Answer: The sample that contains the greater number of molecules is water.
Explanation: To calculate the number of molecules, it is used the Avogadro's number ( 
particles/molecules). So, considering that the mass to water and carbon dioxide is 1g (it can be any other number), the relationship between moles and molar weight is:
To water: 
= 0.05 moles.
Therefore,
1 mol ---- molecules
0.05 moles ---- x
x = 
molecules of water.
To carbon dioxide: 
= 0.02 moles.
Therefore,
1 mol ---- molecules
0.02 moles ---- y
y = 
molecules of carbon dioxide.
