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natita [175]
3 years ago
11

(chem) which is more concentrated: 45.0 grams of HCOOH dissolved in 189 mL of water or 1.5 moles of CH↓2COOH dissolved in twice

as much water?​
Chemistry
1 answer:
Liula [17]3 years ago
6 0

Answer:

CH3COOH would be more concentrated

Explanation:

The higher the concentration value, the more concentrated it is.

The relationship between concentration, moles and volume is given by the equation;

Concentration = No of moles / Volume

5.0 grams of HCOOH dissolved in 189 mL of water

Number of moles = Mass / Molar mass = 5 / 46.03 = 0.1086 mol

Concentration = 0.1086 / 0.189 = 0.5746 mol/L

1.5 moles of CH3COOH dissolved in twice as much water

Volume = 2 * 189 = 378 ml = 0.378 L

Concentration = 1.5 / 0.378 = 3.9683 mol/L

Comparing both concentration values;

CH3COOH would be more concentrated

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Consider the mechanism. Step 1: A+B↽−−⇀CA+B↽−−⇀C equilibrium Step 2: C+A⟶DC+A⟶D slow Overall: 2A+B⟶D2A+B⟶D Determine the rate la
tatuchka [14]

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rate = k[A][B] where k = k₂K

Explanation:

Your mechanism is a slow step with a prior equilibrium:

\begin{array}{rrcl}\text{Step 1}:& \text{A + B} & \xrightarrow [k_{-1}]{k_{1}} & \text{C}\\\text{Step 2}: & \text{C + A} & \xrightarrow [ ]{k_{2}} & \text{D}\\\text{Overall}: & \text{2A + B} & \longrightarrow \, & \text{D}\\\end{array}

(The arrow in Step 1 should be equilibrium arrows).

1. Write the rate equations:

-\dfrac{\text{d[A]}}{\text{d}t} = -\dfrac{\text{d[B]}}{\text{d}t} = -k_{1}[\text{A}][\text{B}] + k_{1}[\text{C}]\\\\\dfrac{\text{d[C]}}{\text{d}t} = k_{1}[\text{A}][\text{B}] - k_{2}[\text{C}]\\\\\dfrac{\text{d[D]}}{\text{d}t} = k_{2}[\text{C}]

2. Derive the rate law

Assume k₋₁ ≫ k₂.  

Then, in effect, we have an equilibrium that is only slightly disturbed by C slowly reacting to form D.  

In an equilibrium, the forward and reverse rates are equal:

k₁[A][B] = k₋₁[C]

[C] = (k₁/k₋₁)[A][B] = K[A][B] (K is the equilibrium constant)

rate = d[D]/dt = k₂[C] = k₂K[A][B] = k[A][B]

The rate law is  

rate = k[A][B] where k = k₂K

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Answer:

Reasonable Second step- N_{2}O(g)+H_{2}(g)\rightarrow N_{2}(g)+H_{2}O(g)

Explanation:

The given single step chemical reaction is as follows.

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Suppose a two-step mechanism is proposed for this reaction,

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