First a balanced reaction equation must be established:

→

Now if mass of aluminum = 145 g
the moles of aluminum = (MASS) ÷ (MOLAR MASS) = 145 g ÷ 30 g/mol
= 4.83 mols
Now the mole ratio of Al : O₂ based on the equation is 4 : 3
[
4Al +
3 O₂ → 2 Al₂O₃]
∴ if moles of Al = 4.83 moles
then moles of O₂ = (4.83 mol ÷ 4) × 3
=
3.63 mol (to 2 sig. fig.)
Thus it can be concluded that
3.63 moles of oxygen is needed to react completely with 145 g of aluminum.
I believe 153.6 is the answer.
C. All the energy stored in the battery had been transformed.
Answer:
The correct answer is option a.
Explanation:

Equilibrium concentration cadmium ions = ![[Cd^{2+}]=0.0585 M](https://tex.z-dn.net/?f=%5BCd%5E%7B2%2B%7D%5D%3D0.0585%20M)
Equilibrium concentration fluoride ions = ![[F^{-}]=0.117 M](https://tex.z-dn.net/?f=%5BF%5E%7B-%7D%5D%3D0.117%20M)
Molar solubility is the maximum concentration of salt present in water in ionic form beyond that no more salt will exist in its ionic form and will settle down in bottom of the solution.
The molar solubility of the solid cadmium fluoride = 0.0585 M
..[1]

Due to addition of sodium fluoride will increase concentration of fluoride in the solution.And due to common ion effect the equilibrium will shift in backward direction in [1], that is precipitation of more cadmium fluoride.
Hence, decrease in solubility will be observed.