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3 years ago

What volume will a gas occupy at 325 K if it occupies 5.8 L at 376 K? Assume the moles and pressure of gas are held constant

Chemistry

1 answer:

Lady_Fox [76]3 years ago

3 0

Answer:

5.01 L

Explanation:

my guy i just took the test, it was this one

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135 grams of sodium has ______ moles. (Enter just the number for this one.)

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Answer : 135 grams of sodium has 5.869 moles.

Solution : Given,

Mass of sodium = 135 grams

Molar mass of sodium = 23 g/mole

Formula used :

$\text{Moles of sodium}=\frac{\text{Mass of sodium}}{\text{Molar mass of sodium}}$

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From the value Kf=1.2×109 for Ni(NH3)62+, calculate the concentration of NH3 required to just dissolve 0.016 mol of NiC2O4 (Ksp

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Answer: The concentration of $NH_3$ required will be 0.285 M.

Explanation:

To calculate the molarity of $NiC_2O_4$ , we use the equation:

$\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}$

Moles of $NiC_2O_4$ = 0.016 moles

Volume of solution = 1 L

Putting values in above equation, we get:

$\text{Molarity of }NiC_2O_4=\frac{0.016mol}{1L}=0.016M$

For the given chemical equations:

$NiC_2O_4(s)\rightleftharpoons Ni^{2+}(aq.)+C_2O_4^{2-}(aq.);K_{sp}=4.0\times 10^{-10}$

$Ni^{2+}(aq.)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K_f=1.2\times 10^9$

Net equation: $NiC_2O_4(s)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K=?$

To calculate the equilibrium constant, K for above equation, we get:

$K=K_{sp}\times K_f\\K=(4.0\times 10^{-10})\times (1.2\times 10^9)=0.48$

The expression for equilibrium constant of above equation is:

$K=\frac{[C_2O_4^{2-}][[Ni(NH_3)_6]^{2+}]}{[NiC_2O_4][NH_3]^6}$

As, $NiC_2O_4$ is a solid, so its activity is taken as 1 and so for $C_2O_4^{2-}$

We are given:

$[[Ni(NH_3)_6]^{2+}]=0.016M$

Putting values in above equations, we get:

$0.48=\frac{0.016}{[NH_3]^6}}$

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Hence, the concentration of $NH_3$ required will be 0.285 M.

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