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Ulleksa [173]
3 years ago
8

From the value Kf=1.2×109 for Ni(NH3)62+, calculate the concentration of NH3 required to just dissolve 0.016 mol of NiC2O4 (Ksp

= 4×10−10) in 1.00 L of solution.
Chemistry
1 answer:
Nina [5.8K]3 years ago
7 0

<u>Answer:</u> The concentration of NH_3 required will be 0.285 M.

<u>Explanation:</u>

To calculate the molarity of NiC_2O_4, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}

Moles of NiC_2O_4 = 0.016 moles

Volume of solution = 1 L

Putting values in above equation, we get:

\text{Molarity of }NiC_2O_4=\frac{0.016mol}{1L}=0.016M

For the given chemical equations:

NiC_2O_4(s)\rightleftharpoons Ni^{2+}(aq.)+C_2O_4^{2-}(aq.);K_{sp}=4.0\times 10^{-10}

Ni^{2+}(aq.)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K_f=1.2\times 10^9

Net equation: NiC_2O_4(s)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K=?

To calculate the equilibrium constant, K for above equation, we get:

K=K_{sp}\times K_f\\K=(4.0\times 10^{-10})\times (1.2\times 10^9)=0.48

The expression for equilibrium constant of above equation is:

K=\frac{[C_2O_4^{2-}][[Ni(NH_3)_6]^{2+}]}{[NiC_2O_4][NH_3]^6}

As, NiC_2O_4 is a solid, so its activity is taken as 1 and so for C_2O_4^{2-}

We are given:

[[Ni(NH_3)_6]^{2+}]=0.016M

Putting values in above equations, we get:

0.48=\frac{0.016}{[NH_3]^6}}

[NH_3]=0.285M

Hence, the concentration of NH_3 required will be 0.285 M.

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