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lisabon 2012 [21]
3 years ago
11

An engine operates on a Carnot cycle that uses 1mole of an ideal gas as the

Chemistry
1 answer:
sattari [20]3 years ago
6 0

Answer:

Step 1;

q = w = -0.52571 kJ, ΔS = 0.876 J/K

Step 2

q = 0, w = ΔU = -7.5 kJ, ΔH = -5.00574 kJ

Explanation:

The given parameters are;

P_i = 100 N·m

T_i = 327 K

P_f = 90 N·m

Step 1

For isothermal expansion, we have;

ΔU = ΔH = 0

w = n·R·T·ln(P_f/P_i) = 1 × 8.314 × 600.15 × ln(90/100) = -525.71

w ≈<em> -0.52571</em> kJ

At state 1, q = w = -0.52571 kJ

ΔS = -n·R·ln(P_f/P_i) = -1 × 8.314 × ln(90/100) ≈ 0.876

ΔS ≈ 0.876 J/K

Step 2

q = 0 for adiabatic process

ΔU = 25×(27 - 327) = -7,500

w = ΔU = <em>-7.5 kJ</em>

ΔH = ΔU + n·R·ΔT

ΔH = -7,500 + 8.3142 × 300 = -5,005.74

ΔH = ΔU = <em>-5.00574 kJ</em>

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30 hot dogs

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3 years ago
A gas occupies 200ml at a temperature of 26 degrees Celsius and 76mmHg pressure. Find the volume at -3degree Celsius with the pr
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Answer:

184.62 ml

Explanation:

Let p_1, v_1, and T_1 be the initial and p_2, v_2, and T_2 be the final pressure, volume, and temperature of the gas respectively.

Given that the pressure remains constant, so

p_1=p_2 ...(i)

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From the ideal gas equation, pv=mRT

Where p is the pressure, v is the volume, T is the temperature in Kelvin, m is the mass of air in kg, R is the specific gas constant.

For the initial condition,

p_1v_1=mRT_1 \\\\mR= \frac{p_1v_1}{T_1}\cdots(ii)

For the final condition,

p_2v_2=mRT_2 \\\\mR= \frac{p_2v_2}{T_2}\cdots(iii)

Equating equation (i), and (ii)

\frac{p_1v_1}{T_1}=\frac{p_2v_2}{T_2}

\frac{v_1}{T_1}=\frac{v_2}{T_2}  [from equation (i)]

v_2=\frac{T_2}{T_1} \times v_1

Putting all the given values, we have

v_2=\frac{276}{299} \times 200 = 184.62 \; ml

Hence, the volume of the gas at 3 degrees Celsius is 184.62 ml.

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3 years ago
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