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viktelen [127]
2 years ago
7

A 52.9g sample of brass, which has a specific heat capacity of 0.375·J·g^−1°C^−1, is put into a calorimeter (see sketch a

t right) that contains 100.0g of water. The temperature of the water starts off at 15.0°C. When the temperature of the water stops changing it's 18.4°C. The pressure remains constant at 1 atm. Calculate the initial temperature of the brass sample.
Chemistry
1 answer:
vaieri [72.5K]2 years ago
7 0

Answer: 90.04°C

Explanation: <u>Calorimeter</u> is a device measures the amount of heat of a chemical or physical process. An ideal calorimeter is one that is well-insulated, i.e., prevent the transfer  of heat between the calorimeter and its surroundings. So, the net heat change inside the calorimeter is zero:

q_{1}+q_{2}=0

Rearraging, it can be written as

q_{1}=-q_{2}

showing that the heat gained by Substance 1 is equal to the energy lost by Substance 2.

In our case, water is gaining heat, because its temperature has risen and so, brass is losing energy:

q_{water}=-q_{brass}

Calculating:

m_{w}.c_{w}.\Delta T=-[m_{b}.c_{b}.\Delta T]

100.4.18.(18.4-15)=-[52.9.0.375.(18.4-T)]

Note: final temperature is the same as the substances are in thermal equilibrium.

Solving:

418(3.4)= - 365.01 + 19.8375T

19.8375T = 1786.21

T = 90.04

The initial temperature for the sample of brass was 90.04°.

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Answer:

1.  [OH⁻] = 0.30 M ; 2. [OH⁻] = 1.54x10⁻⁶M ; 3. [OH⁻] = 1.32x10⁻¹³M

Explanation:

Remember the rule:

pH + pOH = 14

pOH = 14 - pH

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1. 14 - 13.48 = 0.52

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2. 14 - 8.19 = 5.81

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3. 14 - 2.12 = 12.88

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6 0
3 years ago
Consider the formation of ammonia in two experiments. (a) to a 1.00-l container at 727°c, 1.30 mol of n2 and 1.65 mol of h2 are
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When it comes to equilibrium reactions, it useful to do ICE analysis. ICE stands for Initial-Change-Equilibrium. You subtract the initial and change to determine the equilibrium amounts which is the basis for Kc. Kc is the equilibrium constant of concentration which is just the ratio of products to reactant. 

Let's do the ICE analysis

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I         0        1.3    1.65
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-------------------------------------
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The variable x is the amount of moles of the substances that reacted. You apply the stoichiometric coefficients by multiplying it by x. Now, we can solve x by:

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For the second part, I am confused with the given reaction because the stoichiometric coefficients do not balance which violates the law of conservation of mass. But you should remember that the Kc values might differ because of the stoichiometric coefficient. For a reaction: aA + bB ⇄ cC, the Kc for this is

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3 years ago
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R  is the general gas constant,

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<em></em>

Knowing that:

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