If a sample is packed poorly, the sample will not heat evenly and will take longer to melt.
The atomic radium increases to the left and downwards on the periodic table.
By that logic, Se has the largest radius.
Answer:
K = Ka/Kb
Explanation:
P(s) + (3/2) Cl₂(g) <-------> PCl₃(g) K = ?
P(s) + (5/2) Cl₂(g) <--------> PCl₅(g) Ka
PCl₃(g) + Cl₂(g) <---------> PCl₅(g) Kb
K = [PCl₃]/ ([P] [Cl₂]⁽³'²⁾)
Ka = [PCl₅]/ ([P] [Cl₂]⁽⁵'²⁾)
Kb = [PCl₅]/ ([PCl₃] [Cl₂])
Since [PCl₅] = [PCl₅]
From the Ka equation,
[PCl₅] = Ka ([P] [Cl₂]⁽⁵'²⁾)
From the Kb equation
[PCl₅] = Kb ([PCl₃] [Cl₂])
Equating them
Ka ([P] [Cl₂]⁽⁵'²⁾) = Kb ([PCl₃] [Cl₂])
(Ka/Kb) = ([PCl₃] [Cl₂]) / ([P] [Cl₂]⁽⁵'²⁾)
(Ka/Kb) = [PCl₃] / ([P] [Cl₂]⁽³'²⁾)
Comparing this with the equation for the overall equilibrium constant
K = Ka/Kb
Here, we should use combined gas law which can be derived from combined gas law, “PV=nRT”. Rearranging, we can get PV/T=nR. Then we can set the two states in the problem together to get
P1V1/T1 = P2V2/T2
Then just plug in and solve algebraically.
Hope this helps