This is a science multiple choice question. I am posting this for the third time because the people who answered it posted a lin
k and when I copied and pasted it to see the answer, it didn't work so please answer correctly without A LINK! Please whoever answers this without posting a link to the answer will be marked brainliest.
I appreciate it, thanks.
I appreciate it, thanks.
2 answers:
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Lowery-Bronsted theory is applied here. Acc. to this theory Base accepts protons and Acids donate proton.
Part 1:
Aniline is less basic than ethylamine because the lone pair on nitrogen (which accepts proton) is not localized. It resonates throughout the conjugated system of phenyl ring. Hence due to unavailability of electrons for accepting proton it is less basic compare to ethylamine. In ethyl amine the lone pair of electron is localized and available to abstract proton.
Part 2:
In this case the alkyl groups attached to -NH₂ (in ethylamine) and -O⁻ (in ethoxide are same (i.e. CH₃-CH₂-). Ethoxide is more basic than ethylamine because ethoxide is a conjugate base of ethanol (pKa value of ethanol = 15.9 very weak acid) and the conjugate base of weak acid is always a strong base. Secondly, the oxygen atom more Electronegative than Nitrogen atom can attract more electron cloud from alkyl group as compared to Nitrogen in ethylamine. Hence, oxygen in ethoxide attains greater electron cloud than the nitrogen in ethylamine. Therefore, it is more basic than ethylamine.
Part 1:
Aniline is less basic than ethylamine because the lone pair on nitrogen (which accepts proton) is not localized. It resonates throughout the conjugated system of phenyl ring. Hence due to unavailability of electrons for accepting proton it is less basic compare to ethylamine. In ethyl amine the lone pair of electron is localized and available to abstract proton.
Part 2:
In this case the alkyl groups attached to -NH₂ (in ethylamine) and -O⁻ (in ethoxide are same (i.e. CH₃-CH₂-). Ethoxide is more basic than ethylamine because ethoxide is a conjugate base of ethanol (pKa value of ethanol = 15.9 very weak acid) and the conjugate base of weak acid is always a strong base. Secondly, the oxygen atom more Electronegative than Nitrogen atom can attract more electron cloud from alkyl group as compared to Nitrogen in ethylamine. Hence, oxygen in ethoxide attains greater electron cloud than the nitrogen in ethylamine. Therefore, it is more basic than ethylamine.
Answer:
the original concentration of A = 0.0817092 M
Explanation:
A reaction is considered to be of first order it it strictly obeys the graphical equation method.
where;
k = the specific rate coefficient = 3.4 × 10⁻⁴ s⁻¹
t = time = 5.0 h = 5.0 × 3600 = 18000 seconds
a = initial concentration = ???
a - x = remaining concentration of initial concentration at time t = 0.00018 mol L⁻¹
a = 0.0817092 M
Thus , the original concentration of A = 0.0817092 M