Answer:
P_2 =0.51 atm
Explanation:
Given that:
Volume (V1) = 2.50 L
Temperature (T1) = 298 K
Volume (V2) = 4.50 L
at standard temperature and pressure;
Pressure (P1) = 1 atm
Temperature (T2) = 273 K
Pressure P2 = ??
Using combined gas law:
<span>Charles' law says "at a constant pressure, the volume of a fixed amount of gas is directly proportional to its absolute temperature".
V </span>α T
Where V is the volume and T is the temperature in Kelvin of the gas. We can use this for two situations as,
V₁/T₁ = V₂/T₂
V₁ = 2.00 L
T₁ = 40.0 ⁰C = 313 K
V₂ = ?
T₂ = 30.0 ⁰C = 303 K
By applying the formula,
2.00 L / 313 K = V₂ / 303 K
V₂ = (2.00 L / 313 K) x 303 K
V₂ = 1.94 L
Hence, the volume of the balloon at 30.0 ⁰C is 1.94 L
In order to solve this, we need to know the standard cell potentials of the half reaction from the given overall reaction.
The half reactions with their standard cell potentials are:
<span>2ClO−3(aq) + 12H+(aq) + 10e- = Cl2(g) + 6H2O(l)
</span><span>E = +1.47
</span>
<span>Br(l) + 2e- = 2Br-
</span><span>E = +1.065
</span>
We solve for the standard emf by subtracting the standard emf of the oxidation from the reducation, so:
1.47 - 1.065 = 0.405 V
