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Naily [24]
3 years ago
5

O H H H H T A K E T A K E T H A T R U B B E R O F F F * C K T H A T H * E M E A T T O M E A T

Chemistry
2 answers:
alukav5142 [94]3 years ago
3 0

I just needed the points. Have a nice day luv!!!!!!!!!

✨❤️◑﹏◐❤️✨

Oduvanchick [21]3 years ago
3 0

Answer:

seems legit

Explanation:

i'm looking for math answer but found this instead, sick

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Answer:

Synthesis

The first reported synthesis of selenium tetrafluoride was by Paul Lebeau in 1907, who treated selenium with fluorine:[1]

Se + 2 F2 → SeF4

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SF4 + SeO2 → SeF4 + SO2

An intermediate in this reaction is seleninyl fluoride (SeOF2).

Other methods of preparation include fluorinating elemental selenium with chlorine trifluoride:

3 Se + 4 ClF3 → 3 SeF4 + 2 Cl2

Structure and bonding

Selenium in SeF4 has an oxidation state of +4. Its shape in the gaseous phase is similar to that of SF4, having a see-saw shape. VSEPR theory predicts a pseudo-trigonal pyramidal disposition of the five electron pairs around the selenium atom. The axial Se-F bonds are 177 pm with an F-Se-F bond angle of 169.2°. The two other fluorine atoms are attached by shorter bonds (168 pm), with an F-Se-F bond angle of 100.6°. In solution at low concentrations this monomeric structure predominates, but at higher concentrations evidence suggests weak association between SeF4 molecules leading to a distorted octahedral coordination around the selenium atom. In the solid the selenium center also has a distorted octahedral environment.

Reactions

In HF, SeF4 behaves as a weak base, weaker than sulfur tetrafluoride, SF4 (Kb= 2 X 10−2):

SeF4 + HF → SeF3+ + HF2−; (Kb = 4 X 10−4)

Ionic adducts containing the SeF3+ cation are formed with SbF5, AsF5, NbF5, TaF5, and BF3.[3] With caesium fluoride, CsF, the SeF5− anion is formed, which has a square pyramidal structure similar to the isoelectronic chlorine pentafluoride, ClF5 and bromine pentafluoride, BrF5.[4] With 1,1,3,3,5,5-hexamethylpiperidinium fluoride or 1,2-dimethylpropyltrimethylammonium fluoride, the SeF62− anion is formed. This has a distorted octahedral shape which contrasts to the regular octahedral shape of the analogous SeCl62−. [5]

Explanation:

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