Answer: -
IE 1 for X = 801
Here X is told to be in the third period.
So n = 3 for X.
For 1st ionization energy the expression is
IE1 = 13.6 x Z ^2 / n^2
Where Z =atomic number.
Thus Z =( n^2 x IE 1 / 13.6)^(1/2)
Z = ( 3^2 x 801 / 13.6 )^ (1/2)
= 23
Number of electrons = Z = 23
Nearest noble gas = Argon
Argon atomic number = 18
Number of extra electrons = 23 – 18 = 5
a) Electronic Configuration= [Ar] 3d34s2
We know that more the value of atomic radii, lower the force of attraction on the electrons by the nucleus and thus lower the first ionization energy.
So more the first ionization energy, less is the atomic radius.
X has more IE1 than Y.
b) So the atomic radius of X is lesser than that of Y.
c) After the first ionization, the atom is no longer electrically neutral. There is an extra proton in the atom.
Due to this the remaining electrons are more strongly pulled inside than before ionization. Hence after ionization, the radii of Y decreases.
- E(Bonds broken) = 1371 kJ/mol reaction
- E(Bonds formed) = 1852 kJ/mol reaction
- ΔH = -481 kJ/mol.
- The reaction is exothermic.
<h3>Explanation</h3>
2 H-H + O=O → 2 H-O-H
There are two moles of H-H bonds and one mole of O=O bonds in one mole of reactants. All of them will break in the reaction. That will absorb
- E(Bonds broken) = 2 × 436 + 499 = 1371 kJ/mol reaction.
- ΔH(Breaking bonds) = +1371 kJ/mol
Each mole of the reaction will form two moles of water molecules. Each mole of H₂O molecules have two moles O-H bonds. Two moles of the molecule will have four moles of O-H bonds. Forming all those bond will release
- E(Bonds formed) = 2 × 2 × 463 = 1852 kJ/mol reaction.
- ΔH(Forming bonds) = - 1852 kJ/mol
Heat of the reaction:
is negative. As a result, the reaction is exothermic.
Where are the following answers?
The answer is a. one. There are three phosphate bonds in the ATP but only the first bond is responsible for the high energy. When this bond break, ATP will change to ADP.
