Answer:
3 > 2> 1
Explanation:
Aromatic compounds undergo electrophilic substitution reaction which passes through a positively charged intermediate to yield the product.
Substituted benzenes may be more or less reactive towards electrophilic aromatic substitution than benzene molecule depending on the nature of the substituent.
Certain substituents increase the ease of reaction of benzene towards aromatic substitution.
If we look at the compounds closely, we will notice that toluene reacts readily with CH3Cl / AlCl3. This is because, the methyl group is electron donating hence it stabilizes the positively charged intermediate produced in the reaction.
Carbonyl compounds are electron withdrawing substituents hence they decrease the magnitude of the positive charge and hence decrease the rate of electrophilic aromatic substitution.
Those waves carry an amount of energy that can be measured. The energy in a wave is determined by two variables. One is amplitude, which is the distance from the rest position of a wave to the top or bottom. Large amplitude waves contain more energy. Wave A has a greater intensity and transfers more energy. Wave B has a greater intensity and transfers more energy. Waves that require matter to transfer energy are mechanical waves. The matter through which a mechanical wave travels is called a medium. A mechanical wave travels as energy is transferred from particle to particle in the medium. There are two kinds of mechanical waves. The greater the waves amplitude the greater the waves energy. ... A wavelength will travel only as long as it has energy to carry. Gamma rays
Gamma rays have the highest energies, the shortest wavelengths, and the highest frequencies. Radio waves, on the other hand, have the lowest energies, longest wavelengths, and lowest frequencies of any type of EM radiation. Electromagnetic waves cause oscillations in electrical and magnetic fields. It is important to remember that all waves transfer energy but they do not transfer matter . For example, if a ball is placed on the surface of a pond when ripples move across it, the ball will move up and down but not outwards with the wave.
Granulated sugar dissolves faster than a sugar cube since it has a higher surface area. A sugar cube has a low surface which takes more time to dissolve.
Answer:
Less
Explanation:
Since [Cu(NH3)4]2+ and [Cu(H2O)6]2+ are Octahedral Complexes the transitions between d-levels explain the majority of the absorbances seen in those chemical compounds. The difference in energy between d-levels is known as ΔOh (ligand-field splitting parameter) and it depends on several factors:
- The nature of the ligand: A spectrochemical series is a list of ligands ordered on ligand strength. With a higher strength the ΔOh will be higher and thus it requires a higher energy light to make the transition.
- The oxidation state of the metal: Higher oxidation states will strength the ΔOh because of the higher electrostatic attraction between the metal and the ligand
A partial spectrochemical series listing of ligands from small Δ to large Δ:
I− < Br− < S2− < Cl− < N3− < F−< NCO− < OH− < C2O42− < H2O < CH3CN < NH3 < NO2− < PPh3 < CN− < CO
Then NH3 makes the ΔOh higher and it requires a higher energy light to make the transition, which means a shorter wavelength.
