Given that, an experiment to measure the enthalpy change for the reaction of aqueous copper(II) sulfate, CuSO4(aq) and zinc, Zn(s) was carried out in a coffee cup calorimeter; the heat of the reaction in the whole system is calculated to be 2218.34 kJ
Heat of reaction (i.e enthalpy of reaction) is the quantity of heat that is required to be added or removed when a chemical reaction is taken place in order to maintain all of the compounds present at the same temperature.
The formula used to calculate the heat of the reaction can be expressed as follows:
Q = mcΔT
where:
- Q = quantity of heat transfer
- m = mass
- c = specific heat of water = 4.18 kJ/g °C (constant)
- ΔT = change in temparature
From the information given:
- The initial temperature (T₁) = 25° C
- The final temperature (T₂) = 91.5° C
∴
The change in temperature i.e. ΔT = T₂ - T₁
ΔT = 91.5° C - 25° C
ΔT = 66.5° C
The number of moles of CuSO₄ = 1.00 mol/dm³ × 50.0 cm³
= 0.05 moles
- Since the molar mass of CuSO₄ = 159.609 g/mol
Then;
Using the relation:
By crossing multiplying;
mass of CuSO₄ = number of moles of CuSO₄ × molar mass of CuSO₄
mass of CuSO₄ = 0.05 moles × 159.609 g/moles
mass of CuSO₄ = 7.9805 grams
∴
Using the formula from above:
Q = mcΔT
Q = 7.9805 g × 4.18 kJ/g °C × 66.5° C
Q = 2218.34 kJ
Therefore, we can conclude that the heat of the reaction is 2218.34 kJ
Learn more about the chemical reaction here:
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<h3>
Answer:</h3>
2.809 L of H₂SO₄
<h3>
Explanation:</h3>
Concept tested: Moles and Molarity
In this case we are give;
Mass of solid sodium hydroxide as 13.20 g
Molarity of H₂SO₄ as 0.235 M
We are required to determine the volume of H₂SO₄ required
<h3>First: We need to write the balanced equation for the reaction.</h3>
- The reaction between NaOH and H₂SO₄ is a neutralization reaction.
- The balanced equation for the reaction is;
2NaOH + H₂SO₄ → Na₂SO₄ + 2H₂O
<h3>Second: We calculate the umber of moles of NaOH used </h3>
- Number of moles = Mass ÷ Molar mass
- Molar mass of NaOH is 40.0 g/mol
Moles of NaOH = 13.20 g ÷ 40.0 g/mol
= 0.33 moles
<h3>Third: Determine the number of moles of the acid, H₂SO₄</h3>
- From the equation, 2 moles of NaOH reacts with 1 mole of H₂SO₄
- Therefore, the mole ratio of NaOH: H₂SO₄ is 2 : 1.
- Thus, Moles of H₂SO₄ = moles of NaOH × 2
= 0.33 moles × 2
= 0.66 moles of H₂SO₄
<h3>Fourth: Determine the Volume of the acid, H₂SO₄ used</h3>
- When given the molarity of an acid and the number of moles we can calculate the volume of the acid.
- That is; Volume = Number of moles ÷ Molarity
In this case;
Volume of the acid = 0.66 moles ÷ 0.235 M
= 2.809 L
Therefore, the volume of the acid required to neutralize the base,NaOH is 2.809 L.
<u>Answer:</u> The amount of water required to prepare given amount of salt is 398.4 mL
<u>Explanation:</u>
To calculate the volume of solution, we use the equation used to calculate the molarity of solution:
We are given:
Molarity of solution = 0.16 M
Given mass of manganese (II) nitrate tetrahydrate = 16 g
Molar mass of manganese (II) nitrate tetrahydrate = 251 g/mol
Putting values in above equation, we get:
Volume of water = Volume of solution = 398.4 mL
Hence, the amount of water required to prepare given amount of salt is 398.4 mL
It deteriorates. Definitely more than when you started.
Answer:
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