Larger molecules experience larger dispersion forces due to more distance of valance of electrons from the nucleus.
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Larger atoms and molecules have stronger dispersion forces than smaller atoms and molecules because in a larger atom or molecule, the valence electrons are present farther from the nuclei than in a smaller molecule.
They are less tightly held to the nuclear charge present in the nucleus and can easily form temporary dipoles so we can conclude that larger molecules experience larger dispersion forces due to more distance of valance of electrons from the nucleus.
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