Use the Ideal Gas Law to find the moles of gas first.
Be sure to convert T from Celsius to Kelvin by adding 273.
Also I prefer to deal with pressure in atm rather than mmHg, so divide the pressure by 760 to get it in atm.
PV = nRT —> n = PV/RT
P = 547 mmHg = 547/760 atm = 0.720 atm
V = 1.90 L
T = 33°C = 33 + 273 K = 306 K
R = 0.08206 L atm / mol K
n = (0.720 atm)(1.90 L) / (0.08206 L atm / mol K)(306 K) = 0.0545 mol of gas
Now divide grams by mol to get the molecular weight.
3.42 g / 0.0545 mol = 62.8 g/mol
Answer : The change in boiling point is, 
Explanation :
Formula used :

where,
= change in boiling point = ?
i = Van't Hoff factor = 3 (for MgI₂ electrolyte)
= boiling point constant for water = 
m = molality = 0.615 m
Now put all the given values in this formula, we get


Therefore, the change in boiling point is, 
There will be chemical reaction(equation4Na+02--2Na20
The fact that you want to yes is funny