Lowery-Bronsted theory is applied here. Acc. to this theory Base accepts protons and Acids donate proton.
Part 1:
Aniline is less basic than ethylamine because the lone pair on nitrogen (which accepts proton) is not localized. It resonates throughout the conjugated system of phenyl ring. Hence due to unavailability of electrons for accepting proton it is less basic compare to ethylamine. In ethyl amine the lone pair of electron is localized and available to abstract proton.
Part 2:
In this case the alkyl groups attached to -NH₂ (in ethylamine) and -O⁻ (in ethoxide are same (i.e. CH₃-CH₂-). Ethoxide is more basic than ethylamine because ethoxide is a conjugate base of ethanol (pKa value of ethanol = 15.9 very weak acid) and the conjugate base of weak acid is always a strong base. Secondly, the oxygen atom more Electronegative than Nitrogen atom can attract more electron cloud from alkyl group as compared to Nitrogen in ethylamine. Hence, oxygen in ethoxide attains greater electron cloud than the nitrogen in ethylamine. Therefore, it is more basic than ethylamine.
Answer: A 59.5 degree celcius
The equation that we will use to solve this problem is :
PV = nRT where:
P is the pressure of gas = 1.8 atm
V is the volume of gas = 18.2 liters
n is the number of moles of gas = 1.2 moles
R is the gas constant = 0.0821
T is the temperature required (calculated in kelvin)
Using these values to substitute in the equation, we find that:
(1.8)(18.2) = (1.2)(0.0821)(T)
T = 332.5 degree kelvin
The last step is to convert the degree kelvin into degree celcius:
T = 332.5 - 273 = 59.5 degree celcius
Answer:
5 g
Explanation:
The heat required to vaporize ice is the sum of
i) Heat required to melt ice at 0°C
ii) Heat required to raise the temperature from 0°C to 100°C
iii) Heat required to vaporize water at 100°C
Thus;
H = nLfus + ncθ + nLvap
H= n(Lfus + cθ + Lvap)
Lfus = 6.01 kJ/mol
Lvap = 41 kJ/mol
c = 75.38
n =?
2100 = n(6.01 + 75.38(100) + 41)
n = 2100 KJ/7585.01 kJ/mol
n = 0.277 moles
Mass of water = number of moles * molar mass
Mass of water = 0.277 moles * 18 g/mol
Mass of water = 5 g
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Answer:
22 kph
Explanation:
You simply divide the distance and the time. 66/3 = 22.