Answer:
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Answer:
Explanation:
The given reaction is exothermic . So ΔH is negative .
Gas is evolving so work done by gas is positive or w is positive.
Change in internal energy that is ΔU is negative.
q = u - w
u is negative , w is positive so q is negative .
Answer: definite proportions.
Explanation:
1) The definite proportions law states that compounds will always have the same kind of atoms (elements) in the same mass proportion (ratios).
2) For example, a molecule of water will alwys have the same mass ratio of hydrogen atoms to oxygen atoms. That is what permits to obtain the chemical formula of the water molecule as H₂O.
The mass of the two hydrogen atoms will be in a fixed ratio respect to the mass of the oxygen atoms.
Then, if you have one reactant in less proportion than the other, respect to the ratio stated by the chemical formula of water, the former will react completely (it is the limiting reactant) with the corresponding (proportional) mass of the later. Then there will be an excess of the later reactant which will not react (will remain unchanged).
The reactants can only react in the proportion defined by the chemical formulas of the final products.
Answer:
See below
Explanation:
Ammonium
is not a molecular ion because it is just a poly-atomic ion. A molecular ion has a "negative or positive charge" as a whole but the positive charge on here is not on the whole. So, it is a poly-atomic ion and not molecular ion.
The reducing agent in the reaction 2Li(s) + Fe(CH₃COO)₂(aq) → 2LiCH₃COO(aq) + Fe(s) is lithium (Li).
The general reaction is:
2Li(s) + Fe(CH₃COO)₂(aq) → 2LiCH₃COO(aq) + Fe(s) (1)
We can write the above reaction in <u>two reactions</u>, one for oxidation and the other for reduction:
Li⁰(s) → Li⁺(aq) + e⁻ (2)
Fe²⁺(aq) + 2e⁻ → Fe⁰(s) (3)
We can see that Li⁰ is oxidizing to Li⁺ (by <u>losing</u> one electron) in the lithium acetate (<em>reaction 2</em>) and that Fe²⁺ in iron(II) acetate is reducing to Fe⁰ (by <u>gaining</u> two <em>electrons</em>) (<em>reaction 3</em>).
We must remember that the reducing agent is the one that will be oxidized by <u>reducing another element</u> and that the oxidizing agent is the one that will be reduced by <u>oxidizing another species</u>.
In reaction (1), the<em> reducing agent</em> is <em>Li</em> (it is oxidizing to Li⁺), and the <em>oxidizing agent </em>is<em> Fe(CH₃COO)₂</em> (it is reducing to Fe⁰).
Therefore, the reducing agent in reaction (1) is lithium (Li).
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