The radioactive decay obeys first order kinetics
the rate law expression for radioactive decay is
![ln\frac{[A_{0}]}{[A_{t}]}=kt](https://tex.z-dn.net/?f=ln%5Cfrac%7B%5BA_%7B0%7D%5D%7D%7B%5BA_%7Bt%7D%5D%7D%3Dkt)
Where
A0 = initial concentration
At = concentration after time "t"
t = time
k = rate constant
For first order reaction the relation between rate constant and half life is:

Let us calculate k
k = 0.693 / 72 = 0.009625 years⁻¹
Given
At = 0.25 A0

time = 144 years
So after 144 years the sample contains 25% parent isotope and 75% daughter isotopes**
Simply two half lives
What are the options? based on the volume it can differ but in general pipettes and graduated cylinder are the best. <span />
Answer: The new volume at different given temperatures are as follows.
(a) 109.81 mL
(b) 768.65 mL
(c) 18052.38 mL
Explanation:
Given:
= 571 mL, 
(a) 
The new volume is calculated as follows.

(b) 
Convert degree Fahrenheit into degree Cesius as follows.

The new volume is calculated as follows.

(c) 
The new volume is calculated as follows.

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