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VARVARA [1.3K]
3 years ago
10

A 2.2 M solution is made by with 0.45 moles of a solute. What is the final volume of this solution?

Chemistry
1 answer:
Savatey [412]3 years ago
7 0

Answer: The final volume of this solution is 0.204 L.

Explanation:

Given: Molarity of solution = 2.2 M

Moles of solute = 0.45 mol

Molarity is the number of moles of solute present divided by volume in liters.

Molarity = \frac{no. of moles}{Volume (in L)}

Substitute the values into above formula as follows.

Molarity = \frac{no. of moles}{Volume (in L)}\\2.2 M = \frac{0.45}{Volume}\\Volume = 0.204 L

Thus, we can conclude that the final volume of this solution is 0.204 L.

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Assuming that x \; \text{L} of the 0.307 \text{mol} \cdot \text{dm}^{-3} sodium hydroxide solution was added to the acetic acid. Based on previous reasoning, x is sufficiently small that acetic acid was in excess, and no hydroxide ion has yet been produced in the solution. The solution would thus contain 0.2000 \times 0.425 - 0.307 \; x = 0.085 - 0.307 \; x moles of acetic acid and 0.307 \; x moles of acetate ions.

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\begin{array}{lccccc}\text{R} & \text{HAc} & \leftrightharpoons & \text{H}^{+} & + & \text{Ac}^{-}\\\text{I} & 0.085 - 0.307 \; x& & 0 & & 0.307 \; x\\\end{array}

The buffer shall have a pH of 4.250, meaning that it shall have an equilibrium proton concentration of 10^{4.250}\; \text{mol}\cdot \text{dm}^{-3}. There were no proton in the buffer solution before the hydrolysis of acetic acid. Therefore the table shall have an increase of 10^{-4.250}\;\text{mol}\cdot \text{dm}^{-3} in proton concentration in the third row. Atoms conserve. Thus the concentration increase of protons by 10^{-4.250}\;\text{mol}\cdot \text{dm}^{-3} would correspond to a decrease in acetic acid concentration and an increase in acetate ion concentration by the same amount. That is:

\begin{array}{lcccccc}\text{R} & \text{HAc} & \leftrightharpoons & \text{H}^{+} & + & \text{Ac}^{-}\\\text{I} & 0.085 - 0.307 \; x& & 0 & & 0.307 \; x\\\text{C} & - 10^{-4.250} & & +10^{-4.250} & & +10^{-4.250} \\\text{E} & 0.085 - 10^{-4.250} - 0.307 \; x& & 10^{-4.250} & & 10^{-4.250} + 0.307 \; x\end{array}

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\text{K}_{a} = [\text{H}^{+}] \cdot [\text{Ac}^{-}] / [\text{HAc}]\\\phantom{\text{K}_{a}} = 10^{-4.250} \times (10^{-4.250} + 0.307 \; x) / (0.085 - 10^{-4.250} - 0.307 \; x)

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Thus it takes 0.0241 \; \text{L} of sodium hydroxide to produce this buffer solution.

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