Question

A. How many atoms of helium gas fill a spherical balloon of diameter 29.6 cm at 19.0°C and 1.00 atm? b. What is the average kinetic energy of the helium atoms?
c. What is the rms speed of the helium atoms?

Answer 1

Answer:

a) 3.39 × 10²³ atoms

b) 6.04 × 10⁻²¹ J

c) 1349.35 m/s

Explanation:

Given:

Diameter of the balloon, d = 29.6 cm = 0.296 m

Temperature, T = 19.0° C = 19 + 273 = 292 K

Pressure, P = 1.00 atm = 1.013 × 10⁵ Pa

Volume of the balloon = $\frac{4}{3}\pi(\frac{d}{2})^3$

or

Volume of the balloon = $\frac{4}{3}\pi(\frac{0.296}{2})^3$

or

Volume of the balloon, V = 0.0135 m³

Now,

From the relation,

PV = nRT

where,

n is the number of moles

R is the ideal gas constant = 8.314  kg⋅m²/s²⋅K⋅mol

on substituting the respective values, we get

1.013 × 10⁵ × 0.0135 = n × 8.314 × 292

or

n = 0.563

1 mol = 6.022 × 10²³ atoms

Thus,

0.563 moles will have = 0.563 × 6.022 × 10²³ atoms = 3.39 × 10²³ atoms

b) Average kinetic energy = $\frac{3}{2}\times K_BT$

where,

Boltzmann constant, $K_B=1.3807\times10^{-23}J/K$

Average kinetic energy = $\frac{3}{2}\times1.3807\times10^{-23}\times292$

or

Average kinetic energy = 6.04 × 10⁻²¹ J

c) rms speed = $\frac{3RT}{m}$

where, m is the molar mass of the Helium = 0.004 Kg

or

rms speed = $\frac{3\times8.314\times292}{0.004}$

or

rms speed = 1349.35 m/s