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2 years ago

Question 12 of 25

Chemistry

1 answer:

NISA [10]2 years ago

8 0

Answer:

B. Equal amounts of all gases have the same volume at the same

conditions

Explanation:

Amedo Avogadro found the relationship between volume of a gas and the number of molecules contained in the volume.

The law states that "equal volumes of all gases at the same temperature and pressure contains equal number of molecules or moles".

The law describes the behavior of gases when involve in chemical reactions. It enables one to change over at will in any statement about gases from volumes to molecules and vice versa.

So, the right option is B which implies that equal amounts of all gases have the same volume at the same conditions.

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Answer:

1. The pH of 1.0 M trimethyl ammonium (pH = 1.01) is lower than the pH of 0.1 M phenol (5.00).

2. The difference in pH values is 4.95.

Explanation:

1. The pH of a compound can be found using the following equation:

$pH = -log([H_{3}O^{+}])$

First, we need to find [H₃O⁺] for trimethyl ammonium and for phenol.

Trimethyl ammonium:

We can calculate [H₃O⁺] using the Ka as follows:

(CH₃)₃NH⁺ + H₂O → (CH₃)₃N + H₃O⁺

1.0 - x x x

$Ka = \frac{[(CH_{3})_{3}N][H_{3}O^{+}]}{[(CH_{3})_{3}NH^{+}]}$

$10^{-pKa} = \frac{x*x}{1.0 - x}$

$10^{-9.80}(1.0 - x) - x^{2} = 0$

By solving the above equation for x we have:

x = 0.097 = [H₃O⁺]

$pH = -log([H_{3}O^{+}]) = -log(0.097) = 1.01$

Phenol:

C₆H₅OH + H₂O → C₆H₅O⁻ + H₃O⁺

1.0 - x x x

$Ka = \frac{[C_{6}H_{5}O^{-}][H_{3}O^{+}]}{[C_{6}H_{5}OH]}$

$10^{-10} = \frac{x^{2}}{1.0 - x}$

$1.0 \cdot 10^{-10}(1.0 - x) - x^{2} = 0$

Solving the above equation for x we have:

x = 9.96x10⁻⁶ = [H₃O⁺]

$pH = -log([H_{3}O^{+}]) = -log(9.99 \cdot 10^{-6}) = 5.00$

Hence, the pH of 1.0 M trimethyl ammonium is lower than the pH of 0.1 M phenol.

2. The difference in pH values for the two acids is:

$\Delta pH = pH_{C_{6}H_{5}OH} - pH_{(CH_{3})_{3}NH^{+}} = 5.00 - 1.01 = 4.95$

Therefore, the difference in pH values is 4.95.

I hope it helps you!

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