Answer:
a)W=12.62 kJ/mol
b)W=12.59 kJ/mol
Explanation:
At T = 100 °C the second and third virial coefficients are
B = -242.5 cm^3 mol^-1
C = 25200 cm^6 mo1^-2
Now according isothermal work of one mole methyl gas is
W=-
a=
b=
from virial equation
And
a=
b=
Now calculate V1 and V2 at given condition
Substitute given values 
= 1 x 10^5 , T = 373.15 and given values of coefficients we get
Solve for V1 by iterative or alternative cubic equation solver we get
Similarly solve for state 2 at P2 = 50 bar we get
Now
a=241.33
b=30780
After performing integration we get work done on the system is
W=12.62 kJ/mol
(b) for Z = 1 + B' P +C' P^2 = PV/RT by performing differential we get
dV=RT(-1/p^2+0+C')dP
Hence work done on the system is
a=
b=
by substituting given limit and P = 1 bar , P2 = 50 bar and T = 373 K we get work
W=12.59 kJ/mol
The work by differ between a and b because the conversion of constant of virial coefficients are valid only for infinite series
Answer:
- def median(l):
- if(len(l) == 0):
- return 0
- else:
- l.sort()
- if(len(l)%2 == 0):
- index = int(len(l)/2)
- mid = (l[index-1] + l[index]) / 2
- else:
- mid = l[len(l)//2]
- return mid
-
- def mode(l):
- if(len(l)==0):
- return 0
-
- mode = max(set(l), key=l.count)
- return mode
-
- def mean(l):
- if(len(l)==0):
- return 0
- sum = 0
- for x in l:
- sum += x
- mean = sum / len(l)
- return mean
-
- lst = [5, 7, 10, 11, 12, 12, 13, 15, 25, 30, 45, 61]
- print(mean(lst))
- print(median(lst))
- print(mode(lst))
Explanation:
Firstly, we create a median function (Line 1). This function will check if the the length of list is zero and also if it is an even number. If the length is zero (empty list), it return zero (Line 2-3). If it is an even number, it will calculate the median by summing up two middle index values and divide them by two (Line 6-8). Or if the length is an odd, it will simply take the middle index value and return it as output (Line 9-10).
In mode function, after checking the length of list, we use the max function to estimate the maximum count of the item in list (Line 17) and use it as mode.
In mean function, after checking the length of list, we create a sum variable and then use a loop to add the item of list to sum (Line 23-25). After the loop, divide sum by the length of list to get the mean (Line 26).
In the main program, we test the three functions using a sample list and we shall get
20.5
12.5
12
<u></u>
has greater effect.
<u>Explanation</u>:
= Temperature of cold reservoir
= Temperature of hot reservoir
when 
is decreased by 't',
= 
when 
is increased by 'T'
