If Ka for HBrO is 2. 8×10^−9 at 25°C, then the value of Kb for BrO− at 25°C is 3.5× 10^(-6).
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What is base dissociation constant?
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The base dissociation constant (Kb) is defined as the measurement of the ions which base can dissociate or dissolve in the aqueous solution. The greater the value of base dissociation constant greater will be its basicity an strength.
The dissociation reaction of hydrogen cyanide can be given as
HCN --- (H+) + (CN-)
Given,
The value of Ka for HCN is 2.8× 10^(-9)
The correlation between base dissociation constant and acid dissociation constant is
Kw = Ka × Kb
Kw = 10^(-14)
Substituting values of Ka and Kw,
Kb = 10^(-14) /{2.8×10^(-9) }
= 3.5× 10^(-6)
Thus, we find that if Ka for HBrO is 2. 8×10^−9 at 25°C, then the value of Kb for BrO− at 25°C is 3.5× 10^(-6).
DISCLAIMER: The above question have mistake. The correct question is given as
Question:
Given that Ka for HBrO is 2. 8×10^−9 at 25°C. What is the value of Kb for BrO− at 25°C?
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Answer:
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For the absorbance of the solution in a 1.00 cm cell at 500 nm is mathematically given as
A’ = 0.16138
<h3>What is the absorbance of the solution in a 1.00 cm cell at 500 nm?</h3>
Absorbance (A) 2 – log (%T) = 2 – log (15.6) = 0.8069
Generally, the equation for the Beer’s law is mathematically given as
A = ε*c*l
0.8069 = ε*c*(5.00 )
ε*c = 0.16138 cm-1
then for when ε*c is constant
l’ = 1.00
A’ = (0.16138 cm-1)*(1.00 cm)
A’ = 0.16138
In conclusion, the absorbance of the solution in a 1.00 cm cell at 500 nm is
A’ = 0.16138
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Answer:
A = 1,13x10¹⁰
Ea = 16,7 kJ/mol
Explanation:
Using Arrhenius law:
ln k = -Ea/R × 1/T + ln(A)
You can graph ln rate constant in x vs 1/T in y to obtain slope: -Ea/R and intercept is ln(A).
Using the values you will obtain:
y = -2006,9 x +23,147
As R = 8,314472x10⁻³ kJ/molK:
-Ea/8,314472x10⁻³ kJ/molK = -2006,9 K⁻¹
<em>Ea = 16,7 kJ/mol</em>
Pre-exponential factor is:
ln A = 23,147
A = e^23,147
<em>A = 1,13x10¹⁰</em>
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I hope it helps!
1. E. None of the Above
2. D. x + y