Answer:
The molar solubility of lead bromide at 298K is 0.010 mol/L.
Explanation:
In order to solve this problem, we need to use the Nernst Equaiton:
![E = E^{o} - \frac{0.0591}{n} log\frac{[ox]}{[red]}](https://tex.z-dn.net/?f=E%20%3D%20E%5E%7Bo%7D%20-%20%5Cfrac%7B0.0591%7D%7Bn%7D%20log%5Cfrac%7B%5Box%5D%7D%7B%5Bred%5D%7D)
E is the cell potential at a certain instant, E⁰ is the cell potential, n is the number of electrons involved in the redox reaction, [ox] is the concentration of the oxidated specie and [red] is the concentration of the reduced specie.
At equilibrium, E = 0, therefore:
![E^{o} = \frac{0.0591}{n} log \frac{[ox]}{[red]} \\\\log \frac{[ox]}{[red]} = \frac{nE^{o} }{0.0591} \\\\log[red] = log[ox] - \frac{nE^{o} }{0.0591}\\\\[red] = 10^{ log[ox] - \frac{nE^{o} }{0.0591}} \\\\[red] = 10^{ log0.733 - \frac{2x5.45x10^{-2} }{0.0591}}\\\\](https://tex.z-dn.net/?f=E%5E%7Bo%7D%20%20%3D%20%5Cfrac%7B0.0591%7D%7Bn%7D%20log%20%5Cfrac%7B%5Box%5D%7D%7B%5Bred%5D%7D%20%5C%5C%5C%5Clog%20%5Cfrac%7B%5Box%5D%7D%7B%5Bred%5D%7D%20%3D%20%5Cfrac%7BnE%5E%7Bo%7D%20%7D%7B0.0591%7D%20%5C%5C%5C%5Clog%5Bred%5D%20%3D%20%20log%5Box%5D%20-%20%20%5Cfrac%7BnE%5E%7Bo%7D%20%7D%7B0.0591%7D%5C%5C%5C%5C%5Bred%5D%20%3D%2010%5E%7B%20log%5Box%5D%20-%20%20%5Cfrac%7BnE%5E%7Bo%7D%20%7D%7B0.0591%7D%7D%20%5C%5C%5C%5C%5Bred%5D%20%3D%2010%5E%7B%20log0.733%20-%20%20%5Cfrac%7B2x5.45x10%5E%7B-2%7D%20%20%7D%7B0.0591%7D%7D%5C%5C%5C%5C)
[red] = 0.010 M
The reduction will happen in the anode, therefore, the concentration of the reduced specie is equivalent to the molar solubility of lead bromide.
Explanation:
Calcium chloride is an ionic compound as it is formed by transfer of an electron to each chlorine atom.
So, being an ionic compound calcium chloride is able to dissociate completely into water.
Hence, the dissociation reaction will be as follows.
Since, two electrons has been lost by single calcium atom. Therefore, calcium atom will have a charge of +2.
Thus, we can conclude that the charge on the calcium ion, in elementary units is +2.
Answer:
- Addition of Ba(OH)2: favors the formation of a precipitate.
- Undergo a chemical reaction forming soluble species.
- Addition of CuSO4 : favors the formation of a precipitate.
Explanation:
Hello,
In this case, since the dissociation reaction of barium sulfate is:
We must analyze the effect of the common ion:
- By adding barium hydroxide, more barium ions will be added to the equilibrium system so the formation of solid barium sulfate will be favored (reaction shifts leftwards towards reactants).
- By adding sodium nitrate, the following reaction will undergo:
So the precipitate will turn into other soluble species.
- By adding copper (II) sulfate, more sulfate ions will be added to the equilibrium system so the formation of solid barium sulfate will be favored (reaction shifts leftwards towards reactants).
All of this is supported by the Le Chatelier's principle.
Best regards.
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