Explanation:
The given reaction equation will be as follows.
![[FeSCN^{2+}] \rightleftharpoons [Fe^{3+}] + [SCN^{-}]](https://tex.z-dn.net/?f=%5BFeSCN%5E%7B2%2B%7D%5D%20%5Crightleftharpoons%20%5BFe%5E%7B3%2B%7D%5D%20%2B%20%5BSCN%5E%7B-%7D%5D)
Let is assume that at equilibrium the concentrations of given species are as follows.
M
M
M
Now, first calculate the value of
as follows.
![K_{eq} = \frac{[Fe^{3+}][SCN^{-}]}{[FeSCN^{2+}]}](https://tex.z-dn.net/?f=K_%7Beq%7D%20%3D%20%5Cfrac%7B%5BFe%5E%7B3%2B%7D%5D%5BSCN%5E%7B-%7D%5D%7D%7B%5BFeSCN%5E%7B2%2B%7D%5D%7D)
= 
= 
Now, according to the concentration values at the re-established equilibrium the value for
will be calculated as follows.
![K_{eq} = \frac{[Fe^{3+}][SCN^{-}]}{[FeSCN^{2+}]}](https://tex.z-dn.net/?f=K_%7Beq%7D%20%3D%20%5Cfrac%7B%5BFe%5E%7B3%2B%7D%5D%5BSCN%5E%7B-%7D%5D%7D%7B%5BFeSCN%5E%7B2%2B%7D%5D%7D)
M
Thus, we can conclude that the concentration of
in the new equilibrium mixture is
M.
Answer:
mole fraction of NaCl = 0.03145.
mole fraction of water = 0.9686.
Explanation:
- Mole fraction is an expression of the concentration of a solution or mixture.
- It is equal to the moles of one component divided by the total moles in the solution or mixture.
- The summation of mole fraction of all mixture components = 1.
mole fraction of NaCl = (no. of moles of NaCl) / (total no. of moles).
<em>no. of moles of NaCl = mass/molar mass </em>= (6.87 g)/(58.44 g/mol) = 0.1176 mol.
<em>no. of moles of water = mass/molar mass</em> = (65.2 g)/(18.0 g/mol) = <em>3.622 mol.</em>
<em></em>
∴ mole fraction of NaCl = (no. of moles of NaCl) / (total no. of moles) = (0.1176 mol)/(0.1176 mol + 3.622 mol) = 0.03145.
<em>∵ mole fraction of NaCl + mole fraction of water = 1.0.</em>
∴ mole fraction of water = 1.0 - mole fraction of NaCl = 1.0 - 0.03145 = 0.9686.
C because a compound is a substance made of at least two atoms bonded together
Answer: 27.09 ppm and 0.003 %.
First, <u>for air pollutants, ppm refers to parts of steam or gas per million parts of contaminated air, which can be expressed as cm³ / m³. </u>Therefore, we must find the volume of CO that represents 35 mg of this gas at a temperature of -30 ° C and a pressure of 0.92 atm.
Note: we consider 35 mg since this is the acceptable hourly average concentration of CO per cubic meter m³ of contaminated air established in the "National Ambient Air Quality Objectives". The volume of these 35 mg of gas will change according to the atmospheric conditions in which they are.
So, according to the <em>law of ideal gases,</em>
PV = nRT
where P, V, n and T are the pressure, volume, moles and temperature of the gas in question while R is the constant gas (0.082057 atm L / mol K)
The moles of CO will be,
n = 35 mg x
x
→ n = 0.00125 mol
We clear V from the equation and substitute P = 0.92 atm and
T = -30 ° C + 273.15 K = 243.15 K
V = 
→ V = 0.0271 L
As 1000 cm³ = 1 L then,
V = 0.0271 L x
= 27.09 cm³
<u>Then the acceptable concentration </u><u>c</u><u> of CO in ppm is,</u>
c = 27 cm³ / m³ = 27 ppm
<u>To express this concentration in percent by volume </u>we must consider that 1 000 000 cm³ = 1 m³ to convert 27.09 cm³ in m³ and multiply the result by 100%:
c = 27.09
x
x 100%
c = 0.003 %
So, <u>the acceptable concentration of CO if the temperature is -30 °C and pressure is 0.92 atm in ppm and as a percent by volume is </u>27.09 ppm and 0.003 %.