We have to know the molarity of solution obtained when 5.71 g of Na₂CO₃.10 H₂O is dissolved in water and made up to 250 cm³ solution.
The molarity of solution obtained when 5.71 g of sodium carbonate-10-water (Na₂CO₃.10 H₂O) is dissolved in water and made up to 250.0 cm^3 solutionis: (A) 0.08 mol dm⁻³
The molarit y of solution means the number of moles of solute present in one litre of solution. Here solute is Na₂CO₃.10 H₂O and solvent is water. Volume of solution is 250 cm³.
Molar mass of Na₂CO₃.10 H₂O is 286 grams which means mass of one mole of Na₂CO₃.10 H₂O is 286 grams.
5.71 grams of Na₂CO₃.10 H₂O is equal to
= 0.0199 moles of Na₂CO₃.10 H₂O. So, 0.0199 moles of Na₂CO₃.10 H₂O present in 250 cm³ volume of solution.
Hence, number of moles of Na₂CO₃.10 H₂O present in one litre (equal to 1000 cm³) of solution is
= 0.0796 moles. So, the molarity of the solution is 0.0796 mol/dm³ ≅ 0.08 mol/dm³
Yes I think & I Belive it moves across the surface
Answer:
[OH⁻] = 4.3 x 10⁻¹¹M in OH⁻ ions.
Explanation:
Assuming the source of the carbonate ion is from a Group IA carbonate salt (e.g.; Na₂CO₃), then 0.115M Na₂CO₃(aq) => 2(0.115)M Na⁺(aq) + 0.115M CO₃²⁻(aq). The 0.115M CO₃²⁻ then reacts with water to give 0.115M carbonic acid; H₂CO₃(aq) in equilibrium with H⁺(aq) and HCO₃⁻(aq) as the 1st ionization step.
Analysis:
H₂CO₃(aq) ⇄ H⁺(aq) + HCO₃⁻(aq); Ka(1) = 4.3 x 10⁻⁷
C(i) 0.115M 0 0
ΔC -x +x +x
C(eq) 0.115M - x x x
≅ 0.115M
Ka(1) = [H⁺(aq)][HCO₃⁻(aq)]/[H₂CO₃(aq)] = [(x)(x)/(0.115)]M = [x²/0.115]M
= 4.3 x 10⁻⁷ => x = [H⁺(aq)]₁ = SqrRt(4.3 x 10⁻⁷ · 0.115)M = 2.32 x 10⁻⁴M in H⁺ ions.
In general, it is assumed that all of the hydronium ion comes from the 1st ionization step as adding 10⁻¹¹ to 10⁻⁷ would be an insignificant change in H⁺ ion concentration. Therefore, using 2.32 x 10⁻⁴M in H⁺ ion concentration, the hydroxide ion concentration is then calculated from
[H⁺][OH⁻] = Kw => [OH⁻] = (1 x 10⁻¹⁴/2.32 x 10⁻⁴)M = 4.3 x 10⁻¹¹M in OH⁻ ions.
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NOTE: The 2.32 x 10⁻⁴M value for [H⁺] is reasonable for carbonic acid solution with pH ≅ 3.5 - 4.0.
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