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OverLord2011 [107]
3 years ago
8

A radical is a reactive intermediate with a single ____________ electron, formed by ____________ of a covalent bond. Allylic rad

icals are stabilized by ____________ , making them ____________ stable than tertiary radicals. A compound that contains an especially weak bond that serves as a source of radicals is called a radical ____________ . Treatment of cyclohexene with N-bromosuccinimide in the presence of light leads to ____________ by ____________ intermediates.
Chemistry
1 answer:
Marina86 [1]3 years ago
5 0

1. A radical is a reactive intermediate with a single ____________ electron, formed by ____________ of a covalent bond.

1. A: Unpaired, and homolysis

2. Allylic radicals are stabilized by ____________ , making them ____________ stable than tertiary radicals.

2. A: Resonance, and more

3. A compound that contains an especially weak bond that serves as a source of radicals is called a radical ____________ .

3. A: Initiator

4. Treatment of cyclohexene with N-bromosuccinimide in the presence of light leads to ____________ by ____________ intermediates.

4. A: Allylic substitution by radical

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Many important biochemicals are organic acids, such as pyruvic acid ( p K a = 2.50 ) and lactic acid ( p K a = 3.86 ) . The conj
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Pyruvic acid: conjugate base

Lactic acid: conjugate base

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The ratio of conjugate base to conjugate acid can be found using the Henderson-Hasselbalch equation when the pH and pKa are known.

pH = pKa + log([A⁻]/[HA])

The equation can be rearranged to solve for the ratio:

pH - pKa = log([A⁻]/[HA])

[A⁻]/[HA] = 10^(pH-pKa)

Now we can calculate the ratio for the pyruvic acid:

[A⁻]/[HA] = 10^(pH-pKa) = 10^(7.4 - 2.50) = 79433

[A⁻] = 79433[HA]

There is a much higher concentration of the conjugate base.

Similarly for lactic acid:

[A⁻]/[HA] = 10^(pH-pKa) = 10^(7.4 - 3.86) = 3467

[A⁻] = 3467[HA]

For lactic acid the conjugate base also dominates at pH 7.4

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How much force is required to accelerate a 22 kg mass at 6 m/s2?s​
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Answer:

<h3>F=132k.gm/s^2</h3>

Explanation:

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