Answer:
=> 1366.120 g/mL.
Explanation:
To determine the formula to use in solving such a problem, you have to consider what you have been given.
We have;
mass (m) = 25 Kg
Volume (v) = 18.3 mL.
From our question, we are to determine the density (rho) of the rock.
The formula:

First let's convert 25 Kg to g;
1 Kg = 1000 g
25 Kg = ?

= 25000 g
Substitute the values into the formula:

= 1366.120 g/mL.
Therefore, the density (rho) of the rock is 1366.120 g/mL.
The balanced equation for the reaction is as follows;
Ca(OH)₂ + 2HBr --> CaBr₂ + 2H₂O
stoichiometry of Ca(OH)₂ to HBr is 1:2
number of Ca(OH)₂ moles reacted - 0.10 mol/L x 0.1000 L = 0.010 mol
Number of HBr moles added - 0.10 mol/L x 0.4000 = 0.040 mol
1 mol of Ca(OH)₂ needs 2 mol of HBr for neutralisation
therefore 0.010 mol of Ca(OH)₂ needs - 0.010 x 2 = 0.020 mol of HBr to be neutralised
but 0.040 mol of HBr has been added therefore number of moles of HBr in excess - 0.040 - 0.020 = 0.020 mol
then pH of the medium can be calculated using the excess H⁺ ions
HBr is a strong acid therefore complete ionization
[HBr] = [H⁺]
[H⁺] = 0.020 mol / (100.0 + 400.0 mL)
= 0.020 mol / 0.5 L
= 0.040 mol/L
pH = -log[H⁺]
pH = - log [0.040 M]
pH = 1.40
pH of the medium is 1.40
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Im pretty positive its A , hope this helps!