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Lorico [155]
3 years ago
8

A 52.0-mL volume of 0.35 M CH3COOH (Ka=1.8×10−5) is titrated with 0.40 M NaOH. Calculate the pH after the addition of 23.0 mL of

NaOH.
Chemistry
1 answer:
Georgia [21]3 years ago
7 0

NaOH reacts with CH3COOH in 1:1 molar ratio to produce CH3COONa 

NaOH + CH3COOH → CH3COONa + H2O 

Mol CH3COOH in 52.0mL of 0.35M solution = 52.0/1000*0.35 = 0.0182 mol CH3COOH 

Mol NaOH in 19.0mL of 0.40M solution = 19.0/1000*0.40 = 0.0076 mol NaOH 

These will react to produce 0.0076 mol CH3COONa and there will be 0.0182 - 0.0076 = 0.0106 mol CH3COOH remaining in solution unreacted . Total volume of solution = 52.0+19.0 = 71mL or 0.071L 

Molarity of CH3COOH = 0.0106/0.071 = 0.1493M 

CH3COONa = 0.0076 / 0.071 = 0.1070M 

pKa acetic acid = - log Ka = -log 1.8*10^-5 = 4.74. 

pH using Henderson - Hasselbalch equation: 

pH = pKa + log ([salt]/[acid]) 

pH = 4.74 + log ( 0.1070/0.1493) 

pH = 4.74 + log 0.717 

pH = 4.74 + (-0.14) 

pH = 4.60.

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3 years ago
A 20.0-milliliter sample of 0.200 M K2CO3 solution is added to 30.0 milliliters of 0.400 M Ba(NO3)2 solution.
jenyasd209 [6]

Answer:

(B) 0.160 M

Explanation:

Considering:

Molarity=\frac{Moles\ of\ solute}{Volume\ of\ the\ solution}

Or,

Moles =Molarity \times {Volume\ of\ the\ solution}

Given :

For K_2CO_3 :

Molarity = 0.200 M

Volume = 20.0 mL

The conversion of mL to L is shown below:

1 mL = 10⁻³ L

Thus, volume = 20.0×10⁻³ L

Thus, moles of K_2CO_3 :

Moles=0.200 \times {20.0\times 10^{-3}}\ moles

Moles of K_2CO_3 = 0.004 moles

For Ba(NO_3)_2 :

Molarity = 0.400 M

Volume = 30.0 mL

The conversion of mL to L is shown below:

1 mL = 10⁻³ L

Thus, volume =30.0×10⁻³ L

Thus, moles of Ba(NO_3)_2 :

Moles=0.400\times {30.0\times 10^{-3}}\ moles

Moles of Ba(NO_3)_2  = 0.012 moles

According to the given reaction:

K_2CO_3_{(aq)}+Ba(NO_3)_2_{(aq)}\rightarrow BaCO_3_{(s)}+2KNO_3_{(aq)}

1 mole of potassium carbonate react with 1 mole of barium nitrate

0.004 moles potassium carbonate react with 0.004 mole of barium nitrate

Moles of barium nitrate  = 0.004 moles

Available moles of barium nitrate  =  0.012 moles

Limiting reagent is the one which is present in small amount. Thus, potassium carbonate is limiting reagent.

The formation of the product is governed by the limiting reagent. So,

1 mole of potassium carbonate gives 1 mole of barium carbonate

Also,

0.004 mole of potassium carbonate gives 0.004 mole of barium carbonate

Mole of barium carbonate = 0.004 moles

Also, consumed barium nitrate = 0.004 moles  (barium ions precipitate with carbonate ions)

Left over moles = 0.012 - 0.004 moles = 0.008 moles

Total volume = 20.0 + 30.0 mL = 50.0 mL = 0.05 L

So, Concentration = 0.008/0.05 M = 0.160 M

<u>(B) is correct.</u>

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