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3 years ago

A sealed reaction vessel initially contains 1.113×10-2 moles of water vapor and 1.490×10-2 moles of CO(g).

Chemistry

1 answer:

Molodets [167]3 years ago

4 0

Answer:

Kc = $\frac{[8.326x10-3]^{1} }{[1.113x10-2]^{1}[1.490x10-2]^{1} }$

Kc = 50.2059

Explanation:

1. Balance the equation

2. Use the Kc formula

Remember that pure substances, like H2 are not included on the Kc formula

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How much energy must be removed from a 94.4 g sample of benzene (molar mass= 78.11 g/mol) at 322.0 K to solidify the sample and

Kay [80]

Answer : The energy removed must be, 29.4 kJ

Explanation :

The process involved in this problem are :

$(1):C_6H_6(l)(322K)\rightarrow C_6H_6(l)(279K)\\\\(2):C_6H_6(l)(279K)\rightarrow C_6H_6(s)(279K)\\\\(3):C_6H_6(s)(279K)\rightarrow C_6H_6(s)(205K)$

The expression used will be:

$Q=[m\times c_{p,l}\times (T_{final}-T_{initial})]+[m\times \Delta H_{fusion}]+[m\times c_{p,s}\times (T_{final}-T_{initial})]$

where,

$Q$ = heat released for the reaction = ?

m = mass of benzene = 94.4 g

$c_{p,s}$ = specific heat of solid benzene = $1.51J/g^oC=1.51J/g.K$

$c_{p,l}$ = specific heat of liquid benzene = $1.73J/g^oC=1.73J/g.K$

$\Delta H_{fusion}$ = enthalpy change for fusion = $-9.8kJ/mol=-\frac{9.8\times 1000J/mol}{78g/mol}=-125.6J/g$

Now put all the given values in the above expression, we get:

$Q=[94.4g\times 1.73J/g.K\times (279-322)K]+[94.4g\times -125.6J/g]+[94.4g\times 1.51J/g.K\times (205-279)K]$

$Q=-29427.312J=-29.4kJ$

Negative sign indicates that the heat is removed from the system.

Therefore, the energy removed must be, 29.4 kJ

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