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babymother [125]
4 years ago
15

Complete the electron-dot structure of s-allylcysteine, showing all lone-pair electrons.

Chemistry
1 answer:
erastova [34]4 years ago
7 0
The structural formula of <span>s-allylcysteine is shown in the picture (top figure). To create its Lewis structure, draw all its bonds between elements. Each single bond contains two electrons. There is an octet rule that must be obeyed by most elements. Each element should be surrounded with 8 electrons. The hydrogen is exempted of this rule. So, there are 4 lone pairs for the S atom, 1 lone pair for the N atom, and 2 lone pairs each for the 2 O atoms.</span>

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Consider the following reaction: CH3OH(g)⇌CO(g)+2H2(g) Part A Calculate ΔG for this reaction at 25 ∘C under the following condit
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<u>Answer:</u> The \Delta G of the reaction at given temperature is -12.964 kJ/mol.

<u>Explanation:</u>

For the given chemical reaction:

CH_3OH(g)\rightleftharpoons CO(g)+2H_2(g)

The expression of K_p for the given reaction:

K_p=\frac{(p_{CO})\times (p_{H_2}^2)}{p_{CH_3OH}}

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p_{CO}=0.140atm\\p_{H_2}=0.180atm\\p_{CH_3OH}=0.850atm

Putting values in above equation, we get:

K_p=\frac{(0.140)\times (0.180)^2}{0.850}\\\\K_p=5.34\times 10^{-3}

To calculate the Gibbs free energy of the reaction, we use the equation:

\Delta G=\Delta G^o+RT\ln K_p

where,

\Delta G = Gibbs' free energy of the reaction = ?

\Delta G^o = Standard gibbs' free energy change of the reaction = 0 J (at equilibrium)

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T = Temperature = 25^oC=[25+273]K=298K

K_p = equilibrium constant in terms of partial pressure = 5.34\times 10^{-3}

Putting values in above equation, we get:

\Delta G=0+(8.314J/K.mol\times 298K\times \ln(5.34\times 10^{-3}))\\\\\Delta G=-12963.96J/mol=-12.964kJ/mol

Hence, the \Delta G of the reaction at given temperature is -12.964 kJ/mol.

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