The Reaction is spontaneous when temperature is 430 K. Hence, Option (C) is correct.
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What is Spontaneous reaction ?</h3>
Reactions are favorable when they result in a decrease in enthalpy and an increase in entropy of the system.
When both of these conditions are met, the reaction occurs naturally.
Spontaneous reaction is a reaction that favors the formation of products at the conditions under which the reaction is occurring.
According to Gibb's equation:
ΔG = ΔH - TΔS
ΔG = Gibbs free energy
ΔH = enthalpy change = +62.4 kJ/mol
ΔS = entropy change = +0.145 kJ/molK
T = temperature in Kelvin
- ΔG = +ve, reaction is non spontaneous
- ΔG = -ve, reaction is spontaneous
- ΔG = 0, reaction is in equilibrium
ΔH - TΔS = 0 for reaction to be spontaneous
T = ΔH / ΔS
Here,
T = 500K
Thus the Reaction is spontaneous when temperature is 500 K.
Learn more about Gibbs free energy here ;
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First, we calculate the mass of the sample:
mass = density x volume
mass = 8.48 x 112.5
mass = 954 grams
Now, we will calculate the mass of each component using its percentage mass, then divide it by its atomic mass to find the moles and finally multiply the number of moles by the number of particles in a mole, that is, 6.02 x 10²³.
Zinc mass = 0.37 x 954
Zinc mass = 352.98 g
Zinc moles = 352.98 / 65
Zinc moles = 5.43
Zinc atoms = 5.43 x 6.02 x 10²³
Zinc atoms = 3.27 x 10²⁴
Copper mass = 0.63 x 954
Copper mass = 601.02 g
Copper moles = 601.02 / 64
Copper moles = 9.39
Copper atoms = 9.39 x 6.02 x 10²³
Copper atoms = 5.56 x 10²⁴
54g ag *(108mol ag/1 g ag) =5832mol ag
Answer:check explanation
Explanation:
(a). HOW THE DISTANCE BETWEEN ELECTRON DONOR AND ACCEPTOR AFFECTS THE RATE OF ELECTRON TRANSFER IN BIOLOGICAL SYSTEM:
Distance between the acceptor and the donor can affect in two ways; short distance and long distance effect.
Short distance causes
electronic orbitals of donor and acceptor directly overlap whereas in LONG DISTANCE reactions this coupling is indirect because of
sequential overlaps of atomic orbitals of the donor, the intervening medium, and the orbitals of the acceptor.
(b). HOW REORGANIZATION ENERGY OF REDOX ACTIVE SPECIE SURROUNDING MEDIUM AFFECTS:
the reorganized energy does not depend on the pre-existing intra molecule electric field. The charge transferred inside the molecule interacts with its aqueous surroundings.
Reorganized energy can be calculated using Poisson-Boltzmann equation.
