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Answer:
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Answer:
phase transition from a solid to a gas
Explanation:
Entropy refers to the degree of disorderliness in a system. The more disorderly a system is, the greater the entropy of the system.
Decrease in the number of moles of a gas decreases the entropy of the system. Similarly, the entropy of solids is less than that of liquids. The entropy of liquids is less than that of gases.
Therefore, a change of phase from solid to gas represents an increase in entropy of the system.
Answer:
![r = k . [CO] .[Cl_{2}]](https://tex.z-dn.net/?f=r%20%3D%20k%20.%20%5BCO%5D%20.%5BCl_%7B2%7D%5D)
Explanation:
Let´s consider the following reaction:
CO + Cl₂ ⇒ COCl₂
The general rate law is:
![r = k . [CO]^{m}. [Cl_{2}]^{n}](https://tex.z-dn.net/?f=r%20%3D%20k%20.%20%5BCO%5D%5E%7Bm%7D.%20%5BCl_%7B2%7D%5D%5E%7Bn%7D)
where,
r is the rate of the reaction
k is the rate constant
[CO] and [Cl₂] are the molar concentrations of each reactant
m and n are the reaction orders for each reactant
Since the reaction is first order in CO, m = 1. The overall order is the sum of all the individual orders. In this case, the overall order m + n = 2. Then,
m + n = 2
n = 2 - m = 2 - 1 = 1
The reaction is first order in Cl₂.
The rate law is:
![r = k . [CO]. [Cl_{2}]](https://tex.z-dn.net/?f=r%20%3D%20k%20.%20%5BCO%5D.%20%5BCl_%7B2%7D%5D)