Answer: A. Exothermic reaction
Explanation: Enthalpy change for a reaction is sum of enthalpy of formation of products minus sum of enthalpy of formation of reactants.
When the energy level of reactants is above as compared to the products, the reaction is exothermic and when its opposite then reaction is endothermic.
From given information, the potential energy diagram starts at 380 kJ means the energy level of reactants is 380 kJ. It ends at 100 kJ means the energy of products is 100 kJ.
Enthalpy of reaction = 100 kJ - 380 kJ
Enthalpy of reaction = -280 kJ
Negative sign of enthalpy change indicates an Exothermic reaction.
write an equation to represent the oxidation of an alcohol.
identify the reagents that may be used to oxidize a given alcohol.
identify the specific reagent that is used to oxidize primary alcohols to aldehydes rather than to carboxylic acids.
identify the product formed from the oxidation of a given alcohol with a specified oxidizing agent.
identify the alcohol needed to prepare a given aldehyde, ketone or carboxylic acid by simple oxidation.
write a mechanism for the oxidation of an alcohol using a chromium(VI) reagent.
The reading mentions that pyridinium chlorochromate (PCC) is a milder version of chromic acid that is suitable for converting a primary alcohol into an aldehyde without oxidizing it all the way to a carboxylic acid. This reagent is being replaced in laboratories by Dess‑Martin periodinane (DMP), which has several practical advantages over PCC, such as producing higher yields and requiring less rigorous reaction conditions. DMP is named after Daniel Dess and James Martin, who developed it in 1983.
This page looks at the oxidation of alcohols using acidified sodium or potassium dichromate(VI) solution. This reaction is used to make aldehydes, ketones and carboxylic acids, and as a way of distinguishing between primary, secondary and tertiary alcohols.
Oxidizing the different types of alcohols
The oxidizing agent used in these reactions is normally a solution of sodium or potassium dichromate(VI) acidified with dilute sulfuric acid. If oxidation occurs, the orange solution containing the dichromate(VI) ions is reduced to a green solution containing chromium(III) ions. The electron-half-equation for this reaction is
Cr2O2−7+14H++6e−→2Cr3++7H2O
Answer is: a) in the presence of a base.
Phenolphthalein is colorless in acidic solutions and pink in basic solutions.
Acid-base indicators are usually weak acids or bases and they are chemical detectors for hydrogen or hydronium cations.
Example for acid-base indicator is phenolphthalein (molecular formula C₂₀H₁₄O₄).
When solution turns phenolphthalein pink, it means it is basic (pH>7).
Answer:
high ph -basic,low pH -acidic
Explanation:
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