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Irina18 [472]
3 years ago
12

Draw a mechanism for this reaction. 5-hydroxypentanoic acid forms 2-oxanone in the presence of acid. draw all missing reactants

and/or products in the appropriate boxes by placing atoms on the canvas and connecting them with bonds. add charges where needed. electron flow arrows should start on an atom or a bond and should end on an atom, bond, or location where a new bond should be created.
Chemistry
1 answer:
Licemer1 [7]3 years ago
3 0

Answer: -

The first step involves protonation of the carbonyl oxygen.

After protonation, the Alcohol oxygen now attacks the carbon of the carbonyl.

Thus a six membered ring is formed with 5 carbon atoms and 1 oxygen atom. The 1st position carbon atom has 2 OH groups.

One of these gets again protonated.

This leaves as water. With the loss of the H+, there results a carbonyl at 1 position.

Thus 5-hydroxypentanoic acid forms a lactone or 2-oxanone in presence of acid.

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Given the following reaction: 3D(g) + E(g) + 2F(g) → 5G(g) + 4H(g)
evablogger [386]

Answer:

Explanation:

Hello,

The law of mass action, allows us to know the required amounts, thus, for this chemical reaction it is:

\frac{1}{-3} \frac{d[D]}{dt} =\frac{1}{-1} \frac{d[E]}{dt} =\frac{1}{-2} \frac{d[F]}{dt} =\frac{1}{5} \frac{d[G]}{dt} =\frac{1}{4} \frac{d[H]}{dt}

Now, we answer:

(a)

\frac{d[H]}{dt}=4*\frac{1}{-3} *(-0.12M/s)=0.16M/s

(b)

\frac{d[E]}{dt}=-1*\frac{1}{5} *(0.2M/s)=-0.04M/s

(c) Since no initial data is specified, we could establish the rate of the reaction as based of the law of mass action:

r=\frac{1}{-3} \frac{d[D]}{dt} =\frac{1}{-1} \frac{d[E]}{dt} =\frac{1}{-2} \frac{d[F]}{dt} =\frac{1}{5} \frac{d[G]}{dt} =\frac{1}{4} \frac{d[H]}{dt}

Thus, any of the available expressions are suitable to quantify the rate of the reaction.

Best regards.

4 0
4 years ago
A 19.0 L helium tank is pressurized to 26.0 atm. When connected to this tank, a balloon will inflate because the pressure inside
vesna_86 [32]

Answer:

The new volume of the balloon when the pressure equalised with the pressure of the atmosphere = 494 L.

The balloon expands by am additional 475 L.

Explanation:

Assuming Helium behaves like an ideal gas and temperature is constant.

According to Boyle's law for ideal gases, at constant temperature,

P₁V₁ = P₂V₂

P₁ = 26 atm

V₁ = 19.0 L

P₂ = 1 atm (the balloon is said to expand till the pressure matches the pressure of the atmpsphere; and the pressure of the atmosphere is 1 atm)

V₂ = ?

P₁V₁ = P₂V₂

(26 × 19) = 1 × V₂

V₂ = 494 L (it is assumed the balloon never bursts)

The new volume of the balloon when the pressure equalised with the pressure of the atmosphere = 494 L.

The balloon expands by am additional 475 L.

Hope this Helps!!!

6 0
3 years ago
What is the equilibrium membrane potential due to na ions if the extracellular concentration of na ions is 142 mm and the intrac
Ganezh [65]

The equilibrium membrane potential is 41.9 mV.

To calculate the membrane potential, we use the <em>Nernst Equation</em>:

<em>V</em>_Na = (<em>RT</em>)/(<em>zF</em>) ln{[Na]_o/[Na]_ i}

where

• <em>V</em>_Na = the equilibrium membrane potential due to the sodium ions

• <em>R</em> = the universal gas constant [8.314 J·K^(-1)mol^(-1)]

• <em>T</em> = the Kelvin temperature

• <em>z</em> = the charge on the ion (+1)

• <em>F </em>= the Faraday constant [96 485  C·mol^(-1) = 96 485 J·V^(-1)mol^(-1)]

• [Na]_o = the concentration of Na^(+) outside the cell

• [Na]_i = the concentration of Na^(+) inside the cell

∴ <em>V</em>_Na =

[8.314 J·K^(-1)mol^(-1) × 293.15 K]/[1 × 96 485 J·V^(-1)mol^(-1)] ln(142 mM/27 mM) = 0.025 26 V × ln5.26 = 1.66× 25.26 mV = 41.9 mV

4 0
3 years ago
Question 1-19
Hunter-Best [27]

The experiment involving the determination of the number of ice cubes required to keep the temperature of the glass under 15 degrees Celcius, the following things have to be kept in mid:

  • The<u> temperature</u> of the surroundings
  • The initial temperature of the <u>glass</u>
  • The <u>number of ice cubes </u>added to the water in the glass

In order to keep into consideration the changing environmental temperatures (which is a variable in the experiment), the experiment had to be conducted daily to get <u><em>accurate results </em></u>keeping into consideration all the factors.

brainly.com/question/11256472

7 0
2 years ago
Which statement best describes the oxidation numbers of the atoms found in magnesium chloride? A. Magnesium has a 2- oxidation n
In-s [12.5K]
B. is the correct answer of your question
6 0
4 years ago
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