Answer:
= 25.05°C
Explanation:
Given:
the value of ΔHcomb (heat of combustion) for dimethylphthalate (C10H10O4) is = 4685 kJ/mol.
mass = 0.905g of dimethylphthalate
molar mass = 194.18g dimethylphthalate
number of moles of dimethylphthalate = ???
= 21.5°C
= 6.15 kJ/°C
= ???
since we have our molar mass and mass of dimethylphthalate ;we can determine the number of moles as;
0.905g of dimethylphthalate × 
number of moles of dimethylphthalate = 0.000466 moles
Heat released = moles of dimethylphthalate × heat of combustion
= 0.000466 moles × 4685 kJ
= 21.84 kJ
∴ Heat absorbed by the calorimeter = 
21.84 kJ =6.15 kJ/°C 
21.84 KJ = 
21.84 KJ = 
- 132.225 kJ
21.84 KJ + 132.225 kJ =
154.065 kJ =
= 
=25.05°C
We have Kc = 4.2 x 10^-2 (given but missing in the question)
and When the balanced equation for this reaction is:
PCl5(g) ↔ PCl3(g) + Cl2(g)
so, according to the Kc formula:
Kc = the concentration of products / the concentration of the reactants
so, to get the concentration of the reactants in equilibrium, the concentration of the products / the concentration of the reactants should equal the Kc value which is given in the question (missing in your question).
So by substitution in Kc formula:
Kc = [PCl3]*[Cl2] / [PCl5]
4.2 x 10^-2 = 0.18 * 0.25 /[PCl5]
∴[PCl5] = 0.18*0.25 / 4.2x10^-2 = 1.07
So the concentration of the reactants in equilibrim = 1.07
Answer:
The correct answer is 574.59 grams.
Explanation:
Based on the given information, the number of moles of NH₃ will be,
= 2.50 L × 0.800 mol/L
= 2 mol
The given pH of a buffer is 8.53
pH + pOH = 14.00
pOH = 14.00 - pH
pOH = 14.00 - 8.53
pOH = 5.47
The Kb of ammonia given is 1.8 * 10^-5. Now pKb = -logKb,
= -log (1.8 ×10⁻⁵)
= 5.00 - log 1.8
= 5.00 - 0.26
= 4.74
Based on Henderson equation:
pOH = pKb + log ([salt]/[base])
pOH = pKb + [NH₄⁺]/[NH₃]
5.47 = 4.74 + log ([NH₄⁺]/[NH₃])
log([NH₄⁺]/[NH₃]) = 5.47-4.74 = 0.73
[NH₄⁺]/[NH₃] = 10^0.73= 5.37
[NH₄⁺ = 5.37 × 2 mol = 10.74 mol
Now the mass of dry ammonium chloride required is,
mass of NH₄Cl = 10.74 mol × 53.5 g/mol
= 574.59 grams.
Metals usually become cations since electrons are negatively charged and when they are lost there are more protons than electrons making a positive net charge in the atom. (cations are positively charged ions while anions are negatively charged ions)
I hope this helps. Let me know if anything is unclear.
