The half-reaction are:
Cd ---> Cd(OH)₂
The oxidation number of Cd changed from 0 to +2. So, the number of mol electron transferred here is 2.
NiO(OH) --> Ni(OH)₂
The oxidation number of Cd changed from +3 to +2. So, the number of mol electron transferred here is 1.
Now, the greatest common factor would be 2. So, we use n=2 for the formula for ΔG°. F is Faraday's constant equal to 96,485 J/mol e.
ΔG° = nFE° = (2)(96,485)(1.5) =<em> 289,455 J</em>
Since volume and temperature are constant, this means that pressure and <u>number of moles</u> are <u>directly </u>proportional. the sample with the largest <u>number of moles</u> will have the <u>high </u>pressure.
Since, the ideal gas equation is also called ideal gas law. So, according to ideal gas equations,
PV = nRT
- P is pressure of the sample
- T is temperature
- V is volume
- n is the number of moles
- R is universal gas constant
At constant volume and temperature the equation become ,
P ∝ nR
since, R is also constant. So, conclusion of the final equation is
P ∝ n
The number of moles and pressure of the sample is directly proportion. So, on increasing number of moles in the sample , pressure of the sample also increases.
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