Answer:
P O 2 = 5.21 atm P C O 2 = 4.79 atm
Explanation:
Hope it helps!
Answer: a. 0.75m (NH4)3PO4 will have the lowest freezing point .
Explanation: Freezing point decreases as the concentration of the solute substance increases. Assuming the same solvent for all of them, for instance water.
∆T= i.Kf.b
∆T= freezing point depression
i= vant Hoff factor
Kf= molality
Assuming water to be the solvent for all Kf=1.86°C/M
VANT HOFF FACTORS :
For (NH4)3PO4
This has 3 ionic bonding and 1 covalent bonding making it 4 bond
Therefore i=4
For CaSO4
This has 1 metallic bond and 1 covalent bond making it 2 bond.
Therefore i=2
For LiCl
This has 1 metallic bond and 1 non metallic bond making it 2 bond.
Therefore i=2
For CH3OH
This has only 1 covalent bond.
Therefore i=1
MOLALITY:
(NH4)3PO4 = 0.75M
CaSO4= 1.0M
LiCl= 1.0M
CH3OH= 1.5M
FREEZING POINT DEPRESSION:
For (NH4)3PO4
∆T= 4×0.75×1.86=5.58°C
For CaSO4
∆T= 2×1.0×1.86=3.72°C
For LiCl
∆T = 2×1.0×1.86= 3.72°C
For CH3OH
∆T= 1×1.5×1.86=2.79°C
REMEMBER THE HIGHER THE FREEZING POINT DEPRESSION THE LOWER THE FREEZING POINT.
FREEZING POINT DEPRESSION IS THE CHANGE IN THE FREEZING POINT PROPORTIONAL TO THE AMOUNT OF SOLUTE ADDED THE THE SOLUTION.
THEREFORE THE ONE WITH THE LOWEST FREEZING POINT IS (NH4)3PO4
Answer:
(b) BeF2 > OF2 > CH3OH
Explanation:
The degree and type of intermolecular forces present in a substance influences its vapour pressure considerably. The greater the magnitude and strength of intermolecular forces in the substance, the lower the vapour pressure of the substance.
BeF2 molecules are held together by weak vanderwaals forces hence BeF2 will exhibit the least degree of intermolecular interaction and have the highest vapour pressure. OF2 molecules are bound together by dipole interactions hence it will exhibit a lower vapour pressure compared to BeF2. CH3OH molecules form hydrogen bonds with water molecules hence it will exhibit the least vapour pressure among the trio.
We can solve this problem using the long hand solution, wherein we 1 by 1 analyze the different equilibrium reactions or by simply using the Henderson Hasselbach equation. The equation is
pH = -log(pKa) + log (salt/acid)
since the acid and the salt have the same concentration, the log (salt/acid) term is equal to zero.
thus
pH = -log(1.73*10-5)
pH = 4.76
please be careful with the negative sign
Both have a continuous light spectra the fluorescent source makes a spectra with more intense bands of mercury
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