Answer:
A. (CH3)3C-I reacts by SN1 mechanism whose rate is independent of nucleophile reactivity.
Explanation:
We must recall that (CH3)3C-I is a tertiary alkyl halide. Tertiary alkyl halides preferentially undergo substitution reaction via SN1 mechanism.
In SN1 mechanism, the rate of reaction depends solely on the concentration of the alkyl halide (unimolecular mechanism) and is independent of the concentration of the nucleophile. As a result of this, both Br^- and Cl^- react at the same rate.
There are two naturally occurring isotopes of gallium: mass of Ga-69 isotope is 68.9256 amu and its percentage abundance is 60.11%, let the mass of other isotope that is Ga-71 be X, the percentage abundance can be calculated as:
%Ga-71=100-60.11=39.89%
Atomic mass of an element is calculated by taking sum of atomic masses of its isotopes multiplied by their percentage abundance.
Thus, in this case:
Atomic mass= m(Ga-69)×%(Ga-69)+X×%(Ga-71)
From the periodic table, atomic mass of Ga is 69.723 amu.
Putting the values,

Thus,

Rearranging,

Therefore, mass of Ga-71 isotope is 70.9246 amu.
Answer: d. both (b) and (c)
Explanation:
Atoms are too small to be seen on microscopes, so we model them based on theories.
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