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grandymaker [24]
3 years ago
9

Based on the crystal-field strengths cl- < f- < h2o < nh3 < h2nc2h4nh2, which octahedral ti (iii) complex below has

its d-d electronic transition at shortest wavelength?
Chemistry
1 answer:
kati45 [8]3 years ago
8 0
<span>Based on the crystal field strength, Cl ligand would give the longest d-d transition when complexed with Ti(III). as this is the weak field ligand and would cause minimum splitting of d orbitals.</span>
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Consider the data presented below. time (s) 0 40 80 120 160 moles of a 0.100 0.067 0.045 0.030 0.020 part a part complete determ
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To determine which order of the reaction it is, first we need to calculate the rate of change of moles.
the data is as follows 
time         0         40        80       120       160
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Q1)
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for the next 40 s
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the 40 s after that
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and A is the only reactant that affects the rate of the reaction

rate = k [A]ᵇ
8.25 × 10⁻⁴ mol/s = k [0.100 mol]ᵇ ----1
5.5 x 10⁻⁴ mol/s = k [0.067 mol]ᵇ   -----2
divide the 2nd equation by the 1st equation
1.5 = [1.49]ᵇ
b is almost equal to 1
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Q2)
to find out the rate constant(k), we have to first state the equation for a first order reaction.
rate = k[A]ᵇ
As A is the only reactant thats considered for the rate equation. 
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b = 1
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rate = k[A]
substituting the values,
8.25 x 10⁻⁴ mol/s = k [0.100 mol]
k = 8.25 x 10⁻⁴ mol/s /0.100mol
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