An atomic mass unit is defined as precisely 1/12 the mass of an atom of carbon-12.
At STP one mole of any gas occupies 22.4 L
moles NO2 = 99.0/22.4 = 4.42
mass NO2 = 4.42 mol x 46.0 g/mol=203 g
B. Two significant figures
Your final answer can only have as many significant figures as the number that has the least amount of significant figures in it, which is (0.0065)
Refer to attachment for your answer