What four factors influence the rate of a homogeneous reaction.

A buffer solution contains 0.306 M C6H5NH3Br and 0.418 M C6H5NH2 (aniline). Determine the pH change when 0.124 mol HCl is added

Ulleksa [173]

Answer: The pH change of the buffer is 0.30

Explanation:

To calculate the pH of basic buffer, we use the equation given by Henderson Hasselbalch:

$pOH=pK_b+\log(\frac{[\text{conjugate acid}]}{[\text{base}]})$

$pOH=pK_b+\log(\frac{[C_6H_5NH_3^+]}{[C_6H_5NH_2]})$ .....(1)

We are given:

$pK_b$ = negative logarithm of base dissociation constant of aniline = 9.13

$[C_6H_5NH_3^+]=0.306M$

$[C_6H_5NH_2]=0.418M$

pOH = ?

Putting values in equation 1, we get:

$pOH=9.13+\log(\frac{0.306}{0.418})\\\\pOH=8.99$

To calculate pH of the solution, we use the equation:

$pH+pOH=14\\pH_{initial}=14-8.99=5.01$

To calculate the molarity, we use the equation:

$\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}$

Moles hydrochloric acid solution = 0.124 mol

Volume of solution = 1 L

Putting values in above equation, we get:

$\text{Molarity of HCl}=\frac{0.124}{1L}\\\\\text{Molarity of HCl}=0.124M$

The chemical reaction for aniline and HCl follows the equation:

$C_6H_5NH_2+HCl\rightarrow C_6H_5NH_3^++Cl^-$

Initial: 0.418 0.124 0.306

Final: 0.294 - 0.430

Calculating the pOH by using using equation 1:

$pK_b$ = negative logarithm of base dissociation constant of aniline = 9.13

$[C_6H_5NH_3^+]=0.430M$

$[C_6H_5NH_2]=0.294M$

pOH = ?

Putting values in equation 1, we get:

$pOH=9.13+\log(\frac{0.430}{0.294})\\\\pOH=9.29$

To calculate pH of the solution, we use the equation:

$pH+pOH=14\\pH_{final}=14-9.29=4.71$

Calculating the pH change of the solution:

$\Delta pH=pH_{initial}-pH_{final}\\\\\Delta pH=5.01-4.71=0.30$

Hence, the pH change of the buffer is 0.30

8 0

3 years ago

ANSWER THESE 5 MULTPLE CHOICE QUESTIONS!!! I'LL GIVE 30 POINTS AND A BRAINIEST:)

Artemon [7]

Answer:

1. B

2.C

3.D

4.Sorry don't this one :(

5.A

Explanation:

please give me at least 20 points ❤

7 0

3 years ago

In step 2, of the experiment, the procedure uses 3.0M NaOH. However, the student notices that the only solution of NaOH is conce

Luda [366]

Answer:

We need 78.9 mL of the 19.0 M NaOH solution

Explanation:

Step 1: Data given

Molarity of the original NaOH solution = 19.0 M

Molarity of the NaOH solution we want to prepare = 3.0 M

Volume of the NaOH solution we want to prepare = 500 mL = 0.500 L

Step 2: Calculate volume of the 19.0 M NaOH solution needed

C1*V1 = C2*V2

⇒with C1 = the concentration of the original NaOH solution = 19.0 M

⇒with V1 = the volume of the original NaOH solution = TO BE DETERMINED

⇒with C2 = the concentration of the NaOH solution we want to prepare = 3.0 M

⇒with V2 = the volume of the NaOH solution we want to prepare = 500 mL = 0.500 L

19.0 M * V2 = 3.0 M * 0.500 L

V2 = (3.0 M * 0.500L) / 19.0 M

V2 = 0.0789 L

We need 0.0789 L

This is 0.0789 * 10^3 mL = 78.9 mL

We need 78.9 mL of the 19.0 M NaOH solution

8 0

3 years ago

Calculate the mean kinetic energy {e1rans) in joules of the following molecules at 350 k: (a) he, (b) co2, and (c) uf6. explain

Lady bird [3.3K]

The mean kinetic energy per molecule is , where is the Boltzmann constant and T is the absolute temperature.

So at 1000°C, the T = 1273.15 K, kB=1.38 × 10-23, therefore the mean kinetic energy is 2.635 × 10⁻²⁰J.

<h3>What is Kinetic energy ?</h3>

The energy an item has as a result of motion is known as kinetic energy.

A force must be applied to an item in order to accelerate it. We must put forth effort in order to apply a force. After the job is finished, energy is transferred to the item, which then moves at a new, constant speed. Kinetic energy is the type of energy that is transmitted and is dependent on the mass and speed attained.

Kinetic energy may be converted into other types of energy and transported between things. A flying squirrel may run into a chipmunk that is standing still, for instance. Some of the squirrel's original kinetic energy may have been transferred to the chipmunk or changed into another kind of energy after the impact.

To view more about kinetic energy, refer to;

brainly.com/question/2972267

#SPJ4

4 0

2 years ago

Morgan wants to compare the weather conditions at her school each day during the week. She decides to measure and record weather

Firlakuza [10]

Answer: Air Temperature

8 0

3 years ago