248.72 g/mol
CuSO4 has a molar mass of 159.62. H2O has a molar mass of 18.02, which is multiplied by 5 to reflect the 5 H2O molecules.
159.62+5(18.02)=249.72 g/mol
The HCl added = 1.25 moles
and the moles of Na2HPO4 = 1 mole
Now when acid is added in the given solution of Na2HPO4
One mole of H+ will react with one mole of Na2HPO4 to given one mole of NaH2PO4
Na2HPO4 + H+ ---> NaH2PO4
Now this one mole formed NaH2PO4 will further react with 0.25 moles of H+ left to form 0.25 moles of H3PO4 and 0.75 moles of NaH2PO4 will remain in the solution
So this will result into formation of a buffer of phosphoric acid and NaH2PO4
NaH2PO4 + H+ ---> H3PO4
pKa of H3PO4 = 2.1
so pH = pKa + log [salt] / [acid] = 2.1 + log [0.75 / 0.25] = 2.58
so the pH will be in between 2.1 to 7.2
Answer:
0.0468 g.
Explanation:
- The decay of radioactive elements obeys first-order kinetics.
- For a first-order reaction: k = ln2/(t1/2) = 0.693/(t1/2).
Where, k is the rate constant of the reaction.
t1/2 is the half-life time of the reaction (t1/2 = 1620 years).
∴ k = ln2/(t1/2) = 0.693/(1620 years) = 4.28 x 10⁻⁴ year⁻¹.
- For first-order reaction: <em>kt = lna/(a-x).</em>
where, k is the rate constant of the reaction (k = 4.28 x 10⁻⁴ year⁻¹).
t is the time of the reaction (t = t1/2 x 8 = 1620 years x 8 = 12960 year).
a is the initial concentration (a = 12.0 g).
(a-x) is the remaining concentration.
∴ kt = lna/(a-x)
(4.28 x 10⁻⁴ year⁻¹)(12960 year) = ln(12)/(a-x).
5.54688 = ln(12)/(a-x).
Taking e for the both sides:
256.34 = (12)/(a-x).
<em>∴ (a-x) = 12/256.34 = 0.0468 g.</em>
The mole fraction of a gaseous compound is equal to the ratio of the vapor pressure of the compound to the total pressure of the vessel. In this case, teh vapor pressure of tehe non-electrolyte is 760 - 745 = 15 mmHg. hence the mole fraction is 15 mm Hg / 760 mmHg equal to 0.0197
