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Naily [24]
2 years ago
13

In the titration of 50. 0 mL of 0. 400 M HCOOH with 0. 150 M LiOH, how many mL of LiOH are required to reach the equivalence poi

nt
Chemistry
1 answer:
mart [117]2 years ago
8 0

The volume of the 0.15 M LiOH solution required to react with 50 mL of 0.4 M HCOOH to the equivalence point is 133.3 mL

<h3>Balanced equation </h3>

HCOOH + LiOH —> HCOOLi + H₂O

From the balanced equation above,

The mole ratio of the acid, HCOOH (nA) = 1

The mole ratio of the base, LiOH (nB) = 1

<h3>How to determine the volume of LiOH </h3>
  • Molarity of acid, HCOOH (Ma) = 0.4 M
  • Volume of acid, HCOOH (Va) = 50 mL
  • Molarity of base, LiOH (Mb) = 0.15 M
  • Volume of base, LiOH (Vb) =?

MaVa / MbVb = nA / nB

(0.4 × 50) / (0.15 × Vb) = 1

20 / (0.15 × Vb) = 1

Cross multiply

0.15 × Vb = 20

Divide both side by 0.15

Vb = 20 / 0.15

Vb = 133.3 mL

Thus, the volume of the LiOH solution needed is 133.3 mL

Learn more about titration:

brainly.com/question/14356286

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g 2BrO3- + 5SnO22-+ H2O5SnO32- + Br2+ 2OH- In the above reaction, the oxidation state of tin changes from to . How many electron
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Answer:

In the above reaction, the oxidation state of tin changes from 2+ to 4+.

10 moles of electrons are transferred in the reaction

Explanation:

Redox reaction is:

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SnO₂²⁻ → SnO₃²⁻

Tin changes the oxidation state from +2 to +4. It has increased it so this is the oxidation from the redox (it released 2 e⁻). We are in basic medium, so we add water in the side of the reaction where we have the highest amount of oxygen. We have 2 O on left side and 3 O on right side so we add 1 water on the right and we complete with OH⁻ in the opposite side to balance the H.  

SnO₂²⁻ + 2OH⁻ → SnO₃²⁻ + 2e⁻ + H₂O <u>Oxidation</u>

BrO₃⁻ →  Br₂

First of all, we have unbalance the bromine, so we add 2 on the BrO₃⁻. We have 6 O in left side and there are no O on the right, so we add 6 H₂O on the left. To balance the H, we must complete with 12OH⁻. Bromate reduces to bromine at ground state, so it gained 5e⁻. We have 2 atoms of Br, so finally it gaines 10 e⁻.

6H₂O + 10 e⁻ + 2BrO₃⁻ →  Br₂ + 12OH⁻ <u>Reduction</u>

In order to balance the main reaction and balance the electrons we multiply  (x5) the oxidation and (x1) the reduciton

(SnO₂²⁻ + 2OH⁻ → SnO₃²⁻ + 2e⁻ + H₂O) . 5

(6H₂O + 10 e⁻ + 2BrO₃⁻ →  Br₂ + 12OH⁻) . 1

5SnO₂²⁻ + 10OH⁻ + 6H₂O + 10 e⁻ + 2BrO₃⁻ → Br₂ + 12OH⁻ + 5SnO₃²⁻ + 10e⁻ + 5H₂O

We can cancel the e⁻ and we substract:

12OH⁻ - 10OH⁻ = 2OH⁻ (on the right side)

6H₂O - 5H₂O = H₂O (on the left side)

2BrO₃⁻ + 5SnO₂²⁻ + H2O ⇄ 5SnO₃²⁻ + Br₂ + 2OH⁻

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Answer:

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For each of the following sublevels, give the n and l values and the number of orbitals: (a) 5s; (b) 3p; (c) 4f
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Answer:

(a) 5s. n = 5. Sublevel s, l = 0. Number of orbitals = 1

(b) 3p. n = 3. Sublevel p, l = 1. Number of orbitals = 3

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Explanation:

The rules for electron quantum numbers are:

1. Shell number, 1 ≤ n

2. Sublevel number, 0 ≤ l ≤ n − 1

So,

(a) 5s. n = 5, shell number 5. Sublevel s, l = 0. Number of orbitals = 2l +1 = 1

(b) 3p. n = 3, shell number 3. Sublevel p, l = 1. Number of orbitals = 2l +1 = 3

(c) 4f. n =4, shell number 4. Sublevel f, l = 3. Number of orbitals =  2l +1 = 7

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