25 gigaseconds is equal to 2,500,000,000,000 centiseconds
Answer:
∆H > 0
∆Srxn <0
∆G >0
∆Suniverse <0
Explanation:
We are informed that the reaction is endothermic. An endothermic reaction is one in which energy is absorbed hence ∆H is positive at all temperatures.
Similarly, absorption of energy leads to a decrease in entropy of the reaction system. Hence the change in entropy of the reaction ∆Sreaction is negative at all temperatures.
The change in free energy for the reaction is positive at all temperatures since ∆S reaction is negative then from ∆G= ∆H - T∆S, we see that given the positive value of ∆H, ∆G must always return a positive value at all temperatures.
Since entropy of the surrounding= - ∆H/T, given that ∆H is positive, ∆S surrounding will be negative at all temperatures. This is so because an endothermic reaction causes the surrounding to cool down.
<h2>Heptene formed is -</h2><h2>

</h2>
Explanation:
The two possibilities when the peroxide is not present
+ HBr →
In presence peroxide,
≡
+ HBr →
- When peroxides are present in the reaction mixture, hydrogen bromide adds to the triple bond of heptane with regioselectivity.
- This reaction is opposite to that of Markovnikov's rule which says that when asymmetrical alkene reacts with a protic acid HX, then the hydrogen of an acid is attached to the carbon with more in number of hydrogen substituents, and the halide (X) group is attached to the carbon with more in number of substituents of alkyl.
- One mole of HBr adds to one mole of 1-heptane.
- The structure of heptene formed is -
