Answer: The number to the left of AC should be 6.
Explanation: The balanced chemical reaction is one in which the number of atoms of each element on the reactant side must be equal to the number of atoms on product side.
The given equation
is unbalanced as the atoms on the reactant side are not same as number of atoms on product side. This equation is called as skeletal equation.
The balanced chemical equation is :

Thus the number to the left of AC is 6.
The answer is 35.4335
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For a closed system, you need two things:
1) a conservation of mass within the boundaries of the system
2) the ability to freely exchange energy to & from the "closed" system with a surrounding external system
So, the answer is <u><em>never</em></u>, since your defining the "system" as the water within the bathtub, and an open bathtub is exposed to evaporation, which is not conserving mass within the defined "system".