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astra-53 [7]
3 years ago
8

Heterocyclic aromatic compounds undergo electrophilic aromatic substitution in a similar fashion to that undergone by benzene wi

th the formation of a resonance-stabilized intermediate. Draw all of the resonance contributors expected when the above compound undergoes bromination

Chemistry
1 answer:
Readme [11.4K]3 years ago
8 0

Answer:

See explanation

Explanation:

When we talk about electrophilic substitution, we are talking about a substitution reaction in which the attacking agent is an electrophile. The electrophile attacks an electron rich area of a compound during the reaction.

The five membered furan ring is aromatic just as benzene. This aromatic structure is maintained during electrophilic substitution reaction. The attack of the electrophile generates a resonance stabilized intermediate whose canonical structures have been shown in the image attached.

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Draw the most stable resonance structure for the intermediate in the electrophilic aromatic bromination of aniline, anisole, and
ASHA 777 [7]

Answer:

Here's what I get

Explanation:

(a) Intermediates

The three structures below represent one contributor to the resonance-stabilized intermediate, in which the lone pair electrons on the heteroatom are participating (the + charge on the heteroatoms do not show up very well).

(b) Relative Stabilities

The relative stabilities decrease in the order shown.

N is more basic than O, so NH₂ is the best electron donating group (EDG) and will best stabilize the positive charge in the ring. However, the lone pair electrons on the N in acetanilide are also involved in resonance with the carbonyl group, so they are not as available for stabilization of the ring.

(c) Relative reactivities

The relative reactivities would be

C₆H₅-NH₂ >  C₆H₅-OCH₃ > C₆H₅-NHCOCH₃

4 0
3 years ago
The alveoli are surrounded by __________ carrying blood to and from the heart.
natka813 [3]
The alveoli are surrounded<span> by tiny blood vessels, called capillaries. The </span>alveoli<span> and capillaries both have very thin walls, which allow the oxygen to pass from the </span>alveoli<span>to the blood. The capillaries then connect to larger blood vessels, called veins, which bring the oxygenated blood from the lungs to the heart.</span>
4 0
3 years ago
The temperature of a sample of water changes from 10°C to 20°C when the water absorbs 100 calories of heat. What is the mass of
Vlad1618 [11]

Answer:

10 g

Explanation:

Right from the start, just by inspecting the values given, you can say that the answer will be  

10 g

.

Now, here's what that is the case.

As you know, a substance's specific heat tells you how much heat is needed to increase the temperature of  

1 g

of that substance by  

1

∘

C

.

Water has a specific heat of approximately  

4.18

J

g

∘

C

. This tells you that in order to increase the temperature of  

1 g

of water by  

1

∘

C

, you need to provide  

4.18 J

of heat.

Now, how much heat would be required to increase the temperature of  

1 g

of water by  

10

∘

C

?

Well, you'd need  

4.18 J

to increase it by  

1

∘

C

, another  

4.18 J

to increase it by another  

1

∘

C

, and so on. This means that you'd need

4.18 J

×

10

=

41.8 J

to increase the temperature of  

1 g

of water by  

10

∘

C

.

Now look at the value given to you. If you need  

41.8 J

to increase the temperature of  

1 g

of water by  

10

∘

C

, what mass of water would require  

10

times as much heat to increase its temperature by  

10

∘

C

?

1 g

×

10

=

10 g

And that's your answer.

Mathematically, you can calculate this by using the equation

q

=

m

⋅

c

⋅

Δ

T

 

, where

q

- heat absorbed/lost

m

- the mass of the sample

c

- the specific heat of the substance

Δ

T

- the change in temperature, defined as final temperature minus initial temperature

Plug in your values to get

418

J

=

m

⋅

4.18

J

g

∘

C

⋅

(

20

−

10

)

∘

C

m

=

418

4.18

⋅

10

=

10 g

5 0
3 years ago
Calculate the mass of 488 moles of calcium carbonate
san4es73 [151]

Answer: 48800g

Explanation:

Using the mathematical relation : Moles = Mass / Molar Mass

Moles = 488

Molar mass of CaCO3 = 40 + 12 + (16 x 3) = 100g/mol

Therefore

488 = mass / 100 = 48800g

6 0
3 years ago
Consider the following reaction at 298K.
lakkis [162]

The true statements are;

  • K < 0
  • Eocel  < 0

<h3>What is a redox reaction?</h3>

We define a redox reaction as one in which a specie is oxidized and another is reduced.

Now;

Eo cell = cell potential = -0.13 V - (+0.34 V) = -0.47 V

n =number of moles of electrons = 2 mole of electrons

K = equilibrium constant

ΔG = change in free energy

Eo cell = 0.0592/n log K

-0.47 =  0.0592/2 log K

log K =  -0.47  * 2/0.0592

K = 1.3 * 10^-16

ΔG = -nFEo cell

ΔG = -(2 * 96500 * -0.47)

ΔG = 90.7kJ

Learn more about Ecell:brainly.com/question/10203847

#SPJ1

8 0
2 years ago
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