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-Dominant- [34]
3 years ago
7

would you expect the N-O bond in HNO2 to be longer, shorter, or the same length as the N-O bonds in NO2^-

Chemistry
1 answer:
prohojiy [21]3 years ago
8 0
Longer, this is because the H in HNO2 is bonded with an oxygen, no longer allowing this structure to have a resonance structure.
NO2 on the other hand has one double bond and one single bond, so it has a resonance structure. And resonance structures are actually one structure so there isn't really a single and double bond, it's actually a 1 and 1/2 bond that calls for a higher bond order.
And I higher bond order will result in a shorter lengths!
I hope this helps out!!! And just out of curiosity, is this off of an AP FRQ packet??
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<u>Explanation:</u>

For the given reaction:

4Fe(s)+3O_2(g)\rightarrow 2Fe_2O_3(s)

The expression for K_c\text{ and }K_p is given by:

K_c=\frac{1}{[O_2]^3}

K_p=\frac{1}{[O_2]^3}

The concentration of solids are taken to be 1, only concentration of gases and liquid states are taken. The pressure of only gases are taken.

Relationship between K_p\text{ and }K_c is given by the expression:

K_p=K_c\times (RT)^{\Delta n_g}

where,

\Delta n_g= number of moles of gaseous products - number of moles of gaseous reactants

R = gas constant

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For the above reaction,

\Delta n_g = number of moles of gaseous products - number of moles of gaseous reactants = 0 - 3 = -3

Hence, the expression for K_p is:

K_p=K_c\times (RT)^{-3}

Therefore, the equation which is wrong is K_p=K_c(RT)^{-5}

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4 years ago
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babunello [35]

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