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3 years ago

At what temperature is a gas likely to have the lowest rate of diffusion? 15° 21° 24° 30°

Chemistry

2 answers:

sergiy2304 [10]3 years ago

8 0

Answer:

At 15° the gas will have lowest rate of diffusion.

Explanation:

Temperature directly affects the kinetic energy of gas molecules. The energy of motion is called kinetic energy. So if we increase the temperature of gas the average kinetic energy of the gas molecules will increase (they will move faster). Due to increase in kinetic energy they will easily diffuse from their higher concentration to lower concentration (which is diffusion).

Hence the rate of diffusion at given temperature will have following increasing order.

15° < 21° < 24° < 30°

Ray Of Light [21]3 years ago

7 0

AT 15°

The rate of diffusion of a gas is directly proportional to the absolute temperature. At lower temperature the gas particles have less kinetic energy than at higher temperature. This makes the particles travel faster at higher temperature than lower temperature.

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3 years ago

If PbI2(s) is dissolved in 1.0MNaI(aq) , is the maximum possible concentration of Pb2+(aq) in the solution greater than, less th

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Answer:

$\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}$

Less than the concentration of Pb2+(aq) in the solution in part ( a )

Explanation:

From the question:

We assume that s to be the solubility of PbI₂.

The equation of the reaction is given as :

PbI₂(s) ⇌ Pb²⁺(aq) + 2I⁻(aq); Ksp = 7 × 10⁻⁹

[Pb²⁺] = s

Then [I⁻] = 2s

$K_{sp} =\text{[Pb$^{2+}$][I$^{-}$]}^{2} = s\times (2s)^{2} = 4s^{3}\\s^{3} = \dfrac{K_{sp}}{4}\\\\s =\mathbf{ \sqrt [3]{\dfrac{K_{sp}}{4}}}\\\\\text{The mathematical expressionthat can be used to determine the value of }\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}$

The Concentration of Pb²⁺ in water is calculated as :

$\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}$

$\mathbf{s =\sqrt [3]{\dfrac{7*10^{-9}}{4}}}$

$\mathbf{s} =\sqrt[3]{1.75*10^{-9}}$

$\mathbf{s} =\mathbf{1.21*10^{-3} \ mol/L }$

The Concentration of Pb²⁺ in 1.0 mol·L⁻¹ NaI

$\mathbf{PbCl{_2}} \leftrightharpoons \ \ \ \ \ \ \ \mathbf{Pb^{2+}} \ \ \ \ \ + \ \ \ \ \ \ \ \mathbf{2 I^-}$

$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \mathbf0} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \mathbf{1.0}$

$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \mathbf{+x} \ \ \ \ \ \ \ \ \ \ \ \ \mathbf{+2x}$

$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \mathbf{+x} \ \ \ \ \ \ \ \ \ \ \ \ \mathbf{1.0+2x}$

The equilibrium constant:

$K_{sp} =[Pb^{2+}}][I^-]^2 \\ \\ K_{sp} = s*(1.0*2s)^2 =7*1.0^{-9} \\ \\ s = 7*10^{-9} \ \ m/L$

It is now clear that maximum possible concentration of Pb²⁺ in the solution is less than that in the solution in part (A). This happens due to the common ion effect. The added iodide ion forces the position of equilibrium to shift to the left, reducing the concentration of Pb²⁺.

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